The hypothetical polyethylene melt at room temperature is of
interest for the purposes of
developing the atomic level modeling of gas solubilities in rubbery
polymers. In the present study, the
gas solubilities in completely amorphous polyethylene are predicted by
extrapolating alkane behavior to
the long chain limit in a Flory−Huggins context. The results are
seen to agree well with a recent
simulation study.
Platinum-loaded NaY zeolite (Pt/NaY) catalysts were synthesized and tested for the aqueous-phase reforming (APR) of methanol and ethanol solutions to produce hydrogen. The APR performance of the Pt/NaY catalysts was compared to the conventional γ-alumina-supported platinum (Pt/γ-Al 2 O 3 ) catalysts. The results have shown that the Pt/NaY catalysts have higher catalytic performance for the APR of methanol and ethanol than the Pt/γ-Al 2 O 3 catalysts.
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