Donagh Courtney scite author profile

In the title compound, [Co(C13H9)(C28H20)], the Co atom is sandwiched between cyclopentadienyl and cyclobutadienyl rings that are inclined at a dihedral angle of 2.6 (3)°. The four phenyl rings are tilted with respect to the cyclobutadienyl plane so that the C4Ph4 unit constitutes a four-bladed propeller. The phenyl ring of the phenyl-alkyne substituent is inclined to the cyclopentadienyl ring at an angle of 34.92 (18)°. The crystal structure is stabilized solely by C—H⋯π interactions which generate a three-dimensional network.

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The preparation, spectroscopy, structure and electrochemistry of some [Co(η4-C4Ph4)(η5-C5H4CC–CHY)], [Fe(η5-C5H5)(η5-C5H4CC–CHY)], and related complexes

Courtney

McAdam

Manning

et al. 2012

Journal of Organometallic Chemistry

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Main group derivatives of a cyclometallated iron carbonyl anion. Crystal structures of Fe(CO)2{P(OPh)3}{(PhO)2POC6H4}(SnPh3) and two isomers of Fe(CO)2{P(OPh)3}{(PhO)2POC6H4}(I)

Courtney

Cromhout

Cunningham

et al. 2002

Inorganica Chimica Acta

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[Co{Ph2P(O)CH2P(O)Ph2}3][CoCl4]·8CHCl3: Crystal structure and formation from [Co2(Ph2PCH2PPh2)(CO)6] in chloroform

Courtney

Müller‐Bunz

Manning

2006

Inorganica Chimica Acta

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Donagh Courtney

Stilbene analogues incorporating the Co(η4-C4Ph4)(η5-C5H4-) end group

The preparation, spectroscopy, structure and electrochemistry of some [Co(η4-C4Ph4)(η5-C5H4R)] complexes

Aldol condensation reactions of [Co(η4-C4Ph4){η5-C5H4C(O)CH3}]

[η⁵-(Phenylethynyl)cyclopentadienyl](η⁴-tetraphenylcyclobutadiene)cobalt(I)

The preparation, spectroscopy, structure and electrochemistry of some [Co(η4-C4Ph4)(η5-C5H4CC–CHY)], [Fe(η5-C5H5)(η5-C5H4CC–CHY)], and related complexes

Main group derivatives of a cyclometallated iron carbonyl anion. Crystal structures of Fe(CO)2{P(OPh)3}{(PhO)2POC6H4}(SnPh3) and two isomers of Fe(CO)2{P(OPh)3}{(PhO)2POC6H4}(I)

[Co{Ph2P(O)CH2P(O)Ph2}3][CoCl4]·8CHCl3: Crystal structure and formation from [Co2(Ph2PCH2PPh2)(CO)6] in chloroform

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Donagh Courtney

Stilbene analogues incorporating the Co(η4-C4Ph4)(η5-C5H4-) end group

The preparation, spectroscopy, structure and electrochemistry of some [Co(η4-C4Ph4)(η5-C5H4R)] complexes

Aldol condensation reactions of [Co(η4-C4Ph4){η5-C5H4C(O)CH3}]

[η5-(Phenylethynyl)cyclopentadienyl](η4-tetraphenylcyclobutadiene)cobalt(I)

The preparation, spectroscopy, structure and electrochemistry of some [Co(η4-C4Ph4)(η5-C5H4CC–CHY)], [Fe(η5-C5H5)(η5-C5H4CC–CHY)], and related complexes

Main group derivatives of a cyclometallated iron carbonyl anion. Crystal structures of Fe(CO)2{P(OPh)3}{(PhO)2POC6H4}(SnPh3) and two isomers of Fe(CO)2{P(OPh)3}{(PhO)2POC6H4}(I)

[Co{Ph2P(O)CH2P(O)Ph2}3][CoCl4]·8CHCl3: Crystal structure and formation from [Co2(Ph2PCH2PPh2)(CO)6] in chloroform

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[η⁵-(Phenylethynyl)cyclopentadienyl](η⁴-tetraphenylcyclobutadiene)cobalt(I)