It has been stated that whereas between-dimension (color x orientation) conjunctions can be searched in a "parallel" fashion, within-dimension (color x color) conjunctions are necessarily searched in a "serial self-terminating" fashion (Wolfe et al., 1990). We explored the effects of practice (within 1-h experimental session) and distractor grouping on within-dimension conjunction search tasks. In Experiments 1 and 3, the stimuli were rectangles formed by two adjacent squares; in Experiment 2, the stimuli were plus signs formed by two segments and an intersection. In Experiments 1 and 2, observers were assigned to one of two experimental conditions: In one, all the distractors shared a simple feature (the color blue); in the other, distractors did not share that simple feature. In the first condition, search became more efficient with practice and observers' performance was characterized by a shallow reaction time (RT) x set size slope; in the second condition, observers' performance did not improve as much with practice. We propose that the differential effects of practice between these two experimental conditions can be explained in terms of distractor grouping induced by the shared color of the distractors. Experiment 3 showed that, with practice, a shallow RT x set size slope characterized observers' search for a color x color target among four different distractors that shared a common color. The present results contradict a main tenet of some current visual search models--namely, that within-dimension conjunctions cannot be searched in parallel, and question the validity of using RT x set size slope functions to distinguish between preattentive versus attentive search.
The irradiation with UV light of a number of 1,2-diaryl-1-tosylstilbenes, in the presence of base, leads to the corresponding phenanthrenes and heterocyclic analogues. These results are consistent with a mechanism involving the base-induced elimination of p-toluenesulfinic acid from an intermediate 9-tosyl-4a,4b-dihydrophenanthrene, formed by photochemical cyclization of the starting 1,2-diaryl-1-tosylstilbenes. [reaction: see text]
Further development of the microelectronic technology requires the growing of stable and passivated dielectric thin films. Photochemical processes are very promising methods to obtain silicon dioxide films for microelectronic purposes. In this article, the aging of silicon oxide films obtained by ArF laser chemical vapor deposition at low temperature is studied. The evolution of the properties of films has been followed up using infrared spectroscopy and ellipsometry, and compared with aging of thermally oxidized silica films. The role of moisture in film aging is also clarified by comparing films exposed to humid and to dry atmospheres. Si–OH groups are incorporated into the film in a specific local bonding environment and relaxation in the film structure takes place while new Si–O groups can be created. Moreover, the dependence of the stability of film properties on the processing parameters is analyzed.
We have developed a useful modification of the classical preparation of phenanthrenes by UV irradiation of stilbenes in the presence of an oxidant. This modification involves the irradiation, in the presence of base, of stilbenes possessing a sulfonyl group linked to the central double bond. We have proved that this protocol can be successfully applied for the synthesis of diverse phenanthrenes and phenanthrenoids.
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