Opportunities for
enhancing solar energy harvesting using photon
upconversion are reviewed. The increasing prominence of bifacial solar
cells is an enabling factor for the implementation of upconversion,
however, when the realistic constraints of current best-performing
silicon devices are considered, many challenges remain before silicon
photovoltaics operating under nonconcentrated sunlight can be enhanced
via lanthanide-based upconversion. A photophysical model reveals that
>1–2 orders of magnitude increase in the intermediate state
lifetime, energy transfer rate, or generation rate would be needed
before such solar upconversion could start to become efficient. Methods
to increase the generation rate such as the use of cosensitizers to
expand the absorption range and the use of plasmonics or photonic
structures are reviewed. The opportunities and challenges for these
approaches (or combinations thereof) to achieve efficient solar upconversion
are discussed. The opportunity for enhancing the performance of technologies
such as luminescent solar concentrators by combining upconversion
together with micro-optics is also reviewed. Triplet–triplet
annihilation-based upconversion is progressing steadily toward being
relevant to lower-bandgap solar cells. Looking toward photocatalysis,
photophysical modeling indicates that current blue-to-ultraviolet
lanthanide upconversion systems are very inefficient. However, hope
remains in this direction for organic upconversion enhancing the performance
of visible-light-active photocatalysts.
Triplet transfer across a surface-anchored metal-organic-framework heterojunction is demonstrated by the observation of triplet-triplet annihilation photon -upconversion in a sensitizer-emitter heterostructure. Upconversion thresholds under 1 mW cm are achieved. In the broader context, the double-electron-exchange mechanism of triplet transfer indicates that the heterojunction quality is sufficient for electrons to move between layers in this solution-processed crystalline heterostructure.
The development of solid materials which are able to upconvert optical radiation into photons of higher energy is attractive for many applications such as photocatalytic cells and photovoltaic devices. However, to fully exploit triplet-triplet annihilation photon energy upconversion (TTA-UC), oxygen protection is imperative because molecular oxygen is an ultimate quencher of the photon upconversion process. So far, reported solid TTA-UC materials have focused mainly on elastomeric matrices with low barrier properties because the TTA-UC efficiency generally drops significantly in glassy and semicrystalline matrices. To overcome this limit, for example, combine effective and sustainable annihilation upconversion with exhaustive oxygen protection of dyes, we prepare a sustainable solid-state-like material based on nanocellulose. Inspired by the structural buildup of leaves in Nature, we compartmentalize the dyes in the liquid core of nanocellulose-based capsules which are then further embedded in a cellulose nanofibers (NFC) matrix. Using pristine cellulose nanofibers, a sustainable and environmentally friendly functional nanomaterial with ultrahigh barrier properties is achieved. Also, an ensemble of sensitizers and emitter compounds are encapsulated, which allow harvesting of the energy of the whole deep-red sunlight region. The films demonstrate excellent lifetime in synthetic air (20.5/79.5, O2/N2)-even after 1 h operation, the intensity of the TTA-UC signal decreased only 7.8% for the film with 8.8 μm thick NFC coating. The lifetime can be further modulated by the thickness of the protective NFC coating. For comparison, the lifetime of TTA-UC in liquids exposed to air is on the level of seconds to minutes due to fast oxygen quenching.
Non-toxic and biocompatible triplet-triplet annihilation upconversion based nanocapsules (size less than 225 nm) were successfully fabricated by the combination of miniemulsion and solvent evaporation techniques. A first type of nanocapsules displays an upconversion spectrum characterized by the maximum of emission at λmax = 550 nm under illumination by red light, λexc = 633 nm. The second type of nanocapsules fluoresces at λmax = 555 nm when excited with deep-red light, λexc = 708 nm. Conventional confocal laser scanning microscopy (CLSM) and flow cytometry were applied to determine uptake and toxicity of the nanocapsules for various (mesenchymal stem and HeLa) cells. Red light (λexc = 633 nm) with extremely low optical power (less than 0.3 μW) or deep-red light (λexc = 708 nm) was used in CLSM experiments to generate green upconversion fluorescence. The cell images obtained with upconversion excitation demonstrate order of magnitude better signal to background ratio than the cell images obtained with direct excitation of the same fluorescence marker.
We
present a method for the fabrication of ultralight upconverting
mats consisting of rigid polymer nanofibers. The mats are prepared
by simultaneously electrospinning an aqueous solution of a polymer
with pronounced oxygen-barrier properties and functional nanocapsules
containing a sensitizer/emitter couple optimized for triplet–triplet
annihilation photon upconversion. The optical functionality of the
nanocapsules is preserved during the electrospinning process. The
nanofibers demonstrate efficient upconversion fluorescence centered
at λmax = 550 nm under low intensity excitation with
a continuous wave laser (λ = 635 nm, power = 5 mW). The pronounced
oxygen-barrier property of the polymer matrix may efficiently prevent
the oxygen penetration so upconversion fluorescence is registered
in ambient atmosphere. The demonstrated method can be used for the
production of upconverting ultralight porous coatings for sensors
or upconverting membranes with
freely variable thickness for solar cells.
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