Sensitivity and pressure range are two significant parameters of pressure sensors. Existing pressure sensors have difficulty achieving both high sensitivity and a wide pressure range. Therefore, we propose a new pressure sensor with a ternary nanocomposite Fe2O3/C@SnO2. The sea urchin-like Fe2O3 structure promotes signal transduction and protects Fe2O3 needles from mechanical breaking, while the acetylene carbon black improves the conductivity of Fe2O3. Moreover, one part of the SnO2 nanoparticles adheres to the surfaces of Fe2O3 needles and forms Fe2O3/SnO2 heterostructures, while its other part disperses into the carbon layer to form SnO2@C structure. Collectively, the synergistic effects of the three structures (Fe2O3/C, Fe2O3/SnO2 and SnO2@C) improves on the limited pressure response range of a single structure. The experimental results demonstrate that the Fe2O3/C@SnO2 pressure sensor exhibits high sensitivity (680 kPa−1), fast response (10 ms), broad range (up to 150 kPa), and good reproducibility (over 3500 cycles under a pressure of 110 kPa), implying that the new pressure sensor has wide application prospects especially in wearable electronic devices and health monitoring.
Diseases such as cardiovascular problems and sleep apnea cause mass deaths annually due to a lack of timely and portable monitoring and alarm measures. Various wearable devices for health monitoring have been intensely researched to reduce mortality. However, these devices themselves can only detect physiological signals; they cannot sound an alarm. Therefore, they must rely on mobile phones or other peripheral devices such as speakers or vibration motors to sound an alarm, which may result in a patient missing the optimal treatment. It is valuable to develop a self-alarm health monitoring device with the dual functions of physiological signal detection and sound alarm simultaneously. A one-step laser-induced graphene (LIG)based electronic skin (E-skin) is fabricated to perform health monitoring and alarm at the same time, which benefit from its both excellent mechanical and acoustical performance. These customized shutter-patterned E-skins have an ultrahigh sensitivity of 316.3 and can detect various biosignals such as wrist pulse, respiratory, etc. They also have a self-alarm function and can sound an alarm when detecting abnormal situations. This study addresses the multifunctional integration required for multisensors, which will open further applications in wearable sensors and health-care devices.
Controlling the duration that information lasts on paper so that it disappears as desired is crucial for information security. However, this area is rarely studied. Here, we report [TEMA]2SbCl5 (1, TEMA+ = methyltriethylammonium), [TEA]2SbCl5 (2, TEA+ = tetraethylammonium), [TEBA]2SbCl5 (3, TEBA+ = benzyltriethylammonium), and [Ph4P]2SbCl5 (4, Ph4P+ = tetraphenylphosphonium) with structure-dependent reversible photoluminescent switching induced by the absorption and thermal release of small guest molecules including H2O, methanol, and ethylene glycol. Comparing the structural disorder levels, bond lengths, and luminescent Stokes shifts of the compounds aided in understanding their selective absorption behavior. Our results indicated that the information duration on the rewritable paper coated with the title compounds is easily tuned by changing the cation of the compounds, the type of guest molecules, and laser heating power. Our study opens previously unidentified avenues for information security and extends the potential applications of rewritable paper.
This study proposes an efficient, facile, and scalable strategy to synthesize in situ heteroatom-doped porous graphene via laser direct writing on the precursor-doped polyimide (PI) film, which is fabricated for the first time through incorporating PI powder and precursors with sodium carboxymethyl cellulose (CMC) binder by a drop-casting and low-temperature drying process. The resulting microsupercapacitors (MSCs) based on the as-prepared heteroatom-doped porous graphene exhibit remarkable capacitive performance. The typical boron-doped MSC prepared on borax-doped polyimide film possesses an ultrahigh areal capacitance of 60.6 mF cm–2 at 0.08 mA cm–2, which is approximately 20 times larger than that of undoped MSC. Furthermore, the boron-doped MSC has impressive cycling stability (with the capacitance retention of 96.3% after 20 000 cycles), exceptional mechanical flexibility, tunable capacitance, and voltage output through arbitrary modular serial and parallel integration. Besides, the nitrogen-doped porous graphene with excellent capacitive performance is also prepared by laser direct scribing on the sulfonated melamine-doped polyimide film, demonstrating excellent scalability and generality of this strategy. Hence, one-step laser direct writing on precursor-doped polyimide films can realize in situ heteroatom doping and generation of hierarchical porous graphene electrodes simultaneously, which opens a new avenue for the facile, cost-effective, and scalable fabrication of heteroatom-doped porous graphene, thus promising for MSCs and various flexible and wearable electronics at large-scale production.
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