[1] The Hellenic subduction zone displays well-defined temporal and spatial variations in subduction rate and offers an excellent natural laboratory for studying the interaction among slab buoyancy, subduction rate, and tectonic deformation. In space, the active Hellenic subduction front is dextrally offset by 100-120 km across the Kephalonia Transform Zone, coinciding with the junction of a slowly subducting Adriatic continental lithosphere in the north (5-10 mm/yr) and a rapidly subducting Ionian oceanic lithosphere in the south (∼35 mm/yr). Subduction rates can be shown to have decreased from late Eocene time onward, reaching 5-12 mm/yr by late Miocene time, before increasing again along the southern portion of the subduction system. Geodynamic modeling demonstrates that the differing rates of subduction and the resultant trench offset arise naturally from subduction of oceanic (Pindos) lithosphere until late Eocene time, followed by subduction of a broad tract of continental or transitional lithosphere (Hellenic external carbonate platform) and then by Miocene entry of high-density oceanic (Ionian) lithosphere into the southern Hellenic trench. Model results yield an initiation age for the Kephalonia Transform of 6-8 Ma, in good agreement with observations. Consistency between geodynamic model results and geologic observations suggest that the middle Miocene and younger deformation of the Hellenic upper plate, including formation of the Central Hellenic Shear Zone, can be quantitatively understood as the result of spatial variations in the buoyancy of the subducting slab. Using this assumption, we make late Eocene, middle Miocene, and Pliocene reconstructions of the Hellenic system that include quantitative constraints from subduction modeling and geologic constraints on the timing and mode of upper plate deformation.

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Extensional faults exposed in the Peloponnesus and mainland Greece, most of which are described here for the first time, record a transition from regional extension of the Aegean domain to the modern tectonic system. The East Peloponnesus Detachment System trends north‐northwest from the southern Peloponnesus to ∼30 km north of the Gulf of Corinth, dips gently northeast, and is late Miocene–early Pliocene in age. It has a minimum displacement of 25–30 km and appears to be the youngest of the regional‐scale extensional systems with significant displacement that formed parallel to the Hellenic arc. The partially coeval East Sterea Extensional System, which extends from the Gulf of Corinth to the Aegean Sea, contains low‐angle normal faults that both crosscut and trend parallel to older structures of the Hellenic arc. Late Miocene to early Pliocene displacement within this zone disrupted the arc‐parallel structures of the Hellenides. Upper Pliocene‐Quaternary normal faults, which trend approximately east‐west and generally dip steeply at the surface, continue the disruption of the Hellenic arc. Much of the subsidence within the Gulf of Corinth appears to be unrelated to the younger faults and is instead related to the motion on the East Peloponnesus Detachment, which crosscuts the modern graben.

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We report on integrated geomorphological, mineralogical, geochemical and biological investigations of the hydrothermal vent field located on the floor of the density-stratified acidic (pH ~ 5) crater of the Kolumbo shallow-submarine arc-volcano, near Santorini. Kolumbo features rare geodynamic setting at convergent boundaries, where arc-volcanism and seafloor hydrothermal activity are occurring in thinned continental crust. Special focus is given to unique enrichments of polymetallic spires in Sb and Tl (±Hg, As, Au, Ag, Zn) indicating a new hybrid seafloor analogue of epithermal-to-volcanic-hosted-massive-sulphide deposits. Iron microbial-mat analyses reveal dominating ferrihydrite-type phases, and high-proportion of microbial sequences akin to "Nitrosopumilus maritimus", a mesophilic Thaumarchaeota strain capable of chemoautotrophic growth on hydrothermal ammonia and CO2. Our findings highlight that acidic shallow-submarine hydrothermal vents nourish marine ecosystems in which nitrifying Archaea are important and suggest ferrihydrite-type Fe3+-(hydrated)-oxyhydroxides in associated low-temperature iron mats are formed by anaerobic Fe2+-oxidation, dependent on microbially produced nitrate.

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