Wood decay fungi (WDF) seem to be particularly suitable for developing myco-materials due to their mycelial texture, ease of cultivation, and lack of sporification. This study focused on a collection of WDF strains that were later used to develop mycelium mats of leather-like materials. Twenty-one WDF strains were chosen based on the color, homogeneity, and consistency of the mycelia. The growth rate of each strain was measured. To improve the consistency and thickness of the mats, an exclusive method (newly patented) was developed. The obtained materials and the corresponding pure mycelia grown in liquid culture were analyzed by both thermogravimetric analysis (TGA) and scanning electron microscopy (SEM) to evaluate the principal components and texture. TGA provided a semi-quantitative indication on the mycelia and mat composition, but it was hardly able to discriminate differences in the production process (liquid culture versus patented method). SEM provided keen insight on the mycelial microstructure as well as that of the mat without considering the composition; however, it was able to determine the hyphae and porosity dimensions. Although not exhaustive, TGA and SEM are complementary methods that can be used to characterize fungal strains based on their desirable features for various applications in bio-based materials. Taking all of the results into account, the Fomitopsis iberica strain seems to be the most suitable for the development of leather-like materials.
This article reports on the formation of pyrolytic carbon/TiO 2 nanocomposite (p-C/TiO 2 ) by pyrolysis of a mixture of the P25 TiO 2 and kraft lignin at 600 • C. The result was characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, UV-visible spectroscopy, electron paramagnetic resonance spectrometry (EPR), thermogravimetry (TGA) and SEM microscopy. Its photocatalytic activity was ascertained using three classes of chemical probes, namely (i) degradation of methylene blue (MB) and rhodamine-B (RhB) dyes in UV light-irradiated aqueous suspensions, (ii) depletion of phenol and (iii) degradation of antibiotics. The p-C/TiO 2 nanocomposite is a strong phisisorbent of both MB and RhB nearly twofold with respect to neat TiO 2 . Although it is nearly twofold more photoactive toward the degradation of MB (0.091 min −1 versus 0.047 min −1 ), it is not with regard to RhB degradation (0.064 min −1 versus 0.060 min −1 ). For the degradation of phenol in aqueous media (pH 3), pristine TiO 2 was far more effective than p-C/TiO 2 for oxygenated suspensions (17.6 × 10 −3 mM min −1 versus 4.3 × 10 −3 mM min −1 ). Under an argon atmosphere, the kinetics were otherwise identical. The activity of the material was tested also for a real application in the degradation of a fluoroquinolone antibiotic such as enrofloxacin (ENR) in tap water. It is evident that the photoactivity of a semiconductor photocatalyst is not a constant, but it does depend on the nature of the substrate used and on the experimental conditions. It is also argued that the use of dyes to assess photocatalytic activities when suspensions are subjected to visible light irradiation is to be discouraged as the dyes act as electron transfer photosensitizers and or can undergo photodegradation from their excited states.
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