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Magnetic-resonance-imaging rheometrical experiments show that concentrated suspensions or emulsions cannot flow steadily at a uniform rate smaller than a critical value (gamma(c)). As a result, a "liquid" region (sheared rapidly, i.e., at a rate larger than gamma(c)) and a "solid" region (static) coexist. The behavior of the fluid in the liquid region follows a simple power-law model, while the extent of the solid region increases with the degree of jamming of the material.

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Although already known for a long time, hydrated lime (HL) attracted a strong interest as an asphalt additive during the 1970s in the USA, when moisture damage and frost became some of the most pressing pavement failure modes of the time. Given its extensive use in the past 40 years, HL is known to be more than a moisture damage additive: it is an "active filler" that also reduces the chemical ageing of the bitumen and stiffens the mastic more than a normal mineral filler above room temperature. These properties impact durability, and HL is now seen as an additive that increases asphalt mixture durability. This article is a literature review on the fundamentals of the effect of HL on asphalt mixtures. The reasons for it being so effective lie in the strong interactions between both the aggregate and the bitumen and a combination of four mechanisms, two on the aggregate and two on the bitumen. HL modifies the surface properties of the aggregate, allowing for the development of surface composition and roughness more favourable to bitumen adhesion. Then, HL can treat the existing clayey particles adhering to the aggregate surface, inhibiting their detrimental effect on the mixture. Also, HL reacts chemically with the acids of the bitumen, which in turn slows down the age hardening kinetics and neutralises the effect of the "bad" adhesion promoters originally present inside the bitumen, enhancing the moisture resistance of the mixture. Finally, the high porosity of HL explains its stiffening effect above room temperature.

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Hydrated lime (HL) is an active filler in some bitumens. Rheological models demonstrate that HL interacts with certain bitumens to develop an adsorbed (interactive) layer around the HL particles. The volume of this layer can be substantial, causing HL to have a much more substantial effect on the bitumen than inert fillers. The level of interaction between HL and bitumen is bitumen dependent. This interaction causes HL to strongly affect high-temperature rheology in certain bitumens, but it has less of an effect in others. The low-temperature stiffening effects of HL are less prominent, and a significant level of fracture toughening (at low temperatures) occurs through the addition of HL. The active nature of HL with certain bitumens is further verified by nuclear magnetic resonance. HL is considered a multifunctional additive with potential benefits to the binder and to the mixture that include resistance to deformation, low-temperature fracture toughening, and increased resistance to age hardening. HL may be competitive with some polymer additives.

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The rheological properties of a suspension of lime in water (lime putty) are studied with the help of creep tests in a wide range of deformations including very small values. The results are compared with those obtained with a cement paste and several similarities between the two systems are observed. It is shown that the apparent yield stress of a lime suspension is the sum of two components: one due to standard reversible colloidal interactions and one due to the formation of a brittle structure associated with the formation of links due to dissolution-precipitation mechanisms. This second component increases with the time of rest as the square root of time, and the corresponding structure irreversibly breaks as soon as some significant deformation has been imposed. We show that similar structures are formed at concentrations between 25 and 34 % (solid volume fraction) and evolve in a similar way when the time is scaled by a factor decreasing with the solid fraction.