Magnetic susceptibility (χ) variations and the behaviour of the ratio of susceptibility to saturation magnetization (χ/Js ) along the loess/palaeosol section at Koriten (NE Bulgaria) are used to deduce climatic changes during the Pleistocene in southeastern Europe. A good correlation of susceptibility variations with the astronomically tuned oxygen isotope record from ODP site 677 enables us to propose a more precise dating of the upper part of the Bulgarian loess complex. Close correspondence between susceptibility and δ18 O records demonstrates the global significance of the palaeoclimatic signal recorded, although differences in relative amplitudes of χ and χ/Js and δ18 O create difficulties in making quantitative estimates of the climatic humidity in the past. The role of local factors affecting the palaeoclimatic mineral magnetic record deduced from the profile studied in Bulgaria is discussed.
S U M M A R YLoess-palaeosol deposits in the lower Danube area represent the southeastern edge of the loess cover in Europe. Detailed rock magnetic investigations of the loess/palaeosol sequence in Viatovo in NE Bulgaria reveal that magnetite and maghemite of very fine superparamagnetic grain size are responsible for the magnetic enhancement of palaeosol units. A detailed palaeoclimatic record is obtained through high-resolution measurements of magnetic susceptibility, frequency dependent magnetic susceptibility and CaCO 3 content. Magnetic proxies indicate a more warm and humid climate during the development of the older palaeosol units (S 4 -S 6 ).
Fast and cost-effective detection of industrial pollution can significantly promote its ecological, economic, and social assessment. A magnetometric method, used for qualitative determination of anthropogenic contamination, meets these requirements but needs further development in more quantitative terms. It could be used successfully in numerous cases when the heavy metals coexist with strongly magnetic iron oxide particles in the source dust. We present an integrated magnetic and geochemical study that examines the utility of magnetometric techniques for rapid, qualitative detection of metallic pollutants in soils and vegetation. The new aspect of our approach, in comparison with previously published articles on this subject, is the combined investigation (magnetic and geochemical) of both soils and vegetation, thus using an additional medium for employing the magnetometry as a pollution proxy at a site. The study area is a small (approximately 3 km2) region in the suburbs of Sofia (Bulgaria), with the main pollution source being a metallurgical factory. Soil samples have been taken from the topmost 20 cm from private gardens, located at different distances from the factory. Vegetation samples were taken from ryegrass (both leaves and roots) and leaves from two kinds of deciduous trees (maple and acacia). The results show that both vegetation and soils are characterized by enhanced magnetic properties, compared to background material, which is due to the presence of magnetite particles of anthropogenic origin accompanying heavy metal emissions. SEM images and microprobe analyses reveal the presence of a significant amount of particles, containing heavy metals (including iron) in vegetation samples taken close to the main pollution source. Correlation analyses show a statistically significant link (correlation coefficients ranging from 0.6 to 0.7) between magnetic susceptibility and the main heavy metals (Cu, Zn, Pb) in soil samples, indicating that the magnetic susceptibility can provide a proxy method for identifying the relative contribution of industrial pollution in soils and vegetation, that is reliable, inexpensive, and less time-consuming than standard chemical analyses.
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