A novel nanosuperabsorbent composite (NSAPC) was prepared by in situ grafting polymerization and cross-linking on to a novel biopolymer of plant origin (complex heteropolysaccharide in nature) in the presence of a clay mineral using a green chemistry technique. The optimization studies of various synthesis parameters, namely, type of clay, backbone/clay ratio, monomer concentration, cross-linker concentration, initiator concentration, quantity of water per unit reaction mass, particle size of backbone, etc., were done. The NSAPC was characterized by X-ray diffraction and scanning electron microscopy. Swelling behavior of NSAPC in response to external stimuli namely salt solutions, fertilizer solutions, temperature, and pH was studied and compared with the performance of P-gel, a commercial superabsorbent material developed earlier in our laboratory. The NSAPC exhibited significant swelling in various environments. Effect of NSAPC on water absorption and retention characteristics of sandy loam soil and soil-less medium was also studied as a function of temperature and tensions. Addition of NSAPC significantly improved the moisture characteristics of plant growth media (both soil and soil-less), showing that it has tremendous potential for diverse applications in moisture stress agriculture.
Amphiphilic copolymers, synthesized from poly(ethylene glycols) and various aliphatic and aromatic diacids, which self-assemble into nanomicellar aggregates in aqueous media, were used to develop controlled release (CR) formulations of thiamethoxam (3-(2-chloro-1,3-thiazol-5-ylmethyl)-5-methyl-1,3,5-oxadiazinan-4-ylidene(nitro)amine) using encapsulation technique Formulations were characterised by Infrared (IR) spectroscopy, Dynamic Light Scattering (DLS) and Transmission Electron Microscope (TEM). Encapsulation efficiency, loading capacity and stability after accelerated storage test of the developed formulations were checked. The kinetics of thiamethoxam, released in sandy loam soil from the different formulations was studied. Release from the commercial formulation was faster than the CR formulations. The time taken for release of 50 % of thiamethoxam ranged from 3.56 to 6.07 days for the CR formulations. Although the diffusion exponent (n value) of thiamethoxam in soil ranged from 0.532 to 0.881 in the tested formulations showing non-Fickian transport. These CR formulations may be used in safer, effective and economic crop protection.
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