Mineral salt components (Na+, Ca2+, K+, Mg2+, etc.) are naturally excluded during the gas hydrate in which water molecules form cavities by hydrogen bonding and guest gas molecules are encapsulated into the cavities to stabilize the overall gas hydrate structure. However, when using refrigerant hydrofluorocarbon-134a (HFC-134a) for guest gas, it resided in resulting brackish water after the desalination process because of its high solubility in water. Jet loop reactors (JLRs) are frequently employed in many commercial applications because of their high mass transfer capabilities. In this study, a semi-batch type JLR was introduced to improve the degassing of HFC-134a from brackish water. The effect of parameters, such as the initial HFC-134a concentration (200–772 mg/L), liquid circulation (40–80 L/min) rate, and air flow rate (10–30 L/min), were studied in this JLR. The removal efficiency and overall volumetric transfer were calculated and it was determined that increasing the air flow rate has a high effect on KLa.
:We prepared sodium carbonate impregnated activated carbon fiber and evaluated its availability for hydrogen sulfide removal by the comparison with the counterpart, sodium carbonate granular impregnated activated carbon. The sodium carbonate impregnated concentration and immersion duration were chosen as two primary parameters. First, the hydrogen sulfide adsorption capacity increased in proportion to the impregnated concentration up to 3 wt%, above which the sodium carbonate impregnated amount rarely showed an increase due to the pore filling effect for both cases. The optimal impregnated concentration was thus set to 3 wt%. Meanwhile, impregnated activated carbon fiber required only half of the immersion duration compared with granular impregnated activated carbon, while showing a 30% increase on the hydrogen sulfide removal capacity. The greater specific area of impregnated activated carbon fiber explained it. In conclusion, we evaluated advantage of preparation time and improved hydrogen sulfide adsorption capacity by impregnate sodium carbonate, which is capable of reacting with hydrogen sulfide chemically, onto the activated carbon fiber with improved specific area.
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