A wide variety of biomass is available all around the world. Most of the biomass exists as a by-product from manufacturing industries. Pulp and paper mills contribute to a higher amount of these biomasses mostly discarded in the landfills creating an environmental burden. Biomasses from other sources have been used to produce different kinds and grades of biomaterials such as those used in industrial and medical applications. The present review aims to investigate the availability of biomass from pulp and paper mills and show sustainable routes for the production of high value-added biomaterials. The study reveals that using conventional and integrated biorefinery technology the ample variety and quantity of waste generated from pulp and paper mills can be converted into wealth. As per the findings of the current review, it is shown that high-performance carbon fiber and bioplastic can be manufactured from black liquor of pulping waste; the cellulosic waste from sawdust and sludge can be utilized for the synthesis of CNC and regenerated fibers such as viscose rayon and acetate; the mineral-based pulping wastes and fly ash can be used for manufacturing of different kinds of biocomposites. The different biomaterials obtained from the pulp and paper mill biomass can be used for versatile applications including conventional, high performance, and smart materials. Through customization and optimization of the conversion techniques and product manufacturing schemes, a variety of engineering materials can be obtained from pulp and paper mill wastes realizing the current global waste to wealth developmental approach.

Cellulose-based hydrogels were prepared by the extraction of cellulose from corncobs after the removal of lignin and hemicellulose with the use of alkali–acid treatment. Acrylate-based hydrogels presently available for personal hygiene uses are not biodegradable. In this study, a biodegradable cellulose-co-AMPS personal hygiene hydrogel was synthesized. The hydrogel was synthesized by graft co-polymerization of 2-acrylamido2-methyl propane sulfonic acid onto corncob cellulose by using potassium persulfate (KPS) as an initiator and borax decahydrate (Na2B4O7·10H2O) as a cross-linking agent. Structural and functional characteristics of the hydrogel such as swelling measurements, antimicrobial tests, FTIR spectra and thermogravimetric analysis were done. The hydrogel showed an average swelling ratio of 279.6 g/g to water and 83.3 g/g to a urine solution with a 97% gel fraction. The hydrogel displayed no clear inhibition zone and did not support the growth of bacteria, Gram-positive or -negative. The FT-IR spectra of the hydrogel confirmed the grafting of an AMPS co-polymer onto cellulose chains. The thermal properties of the hydrogel showed three-step degradation, with a complete degradation temperature of 575 °C.

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The meat processing industry produces a huge quantity of by-products, approximately 150 million tonnes per year. The live weight of the animals is distinguished as edible, inedible, and discardable by-products, with the discardable parts equating to 66%, 52%, and 80% of the overall live weight of cattle, lamb, and pigs, respectively. Only a small percentage of those by-products are nowadays exploited for the production of high added value products such as animal feed, glue, fertilizers, etc., whereas the main management method is direct disposal to landfills. As such, the current disposal methodologies of these by-products are problematic, contributing to environmental contamination, soil degradation, air pollution, and possible health problems. Nevertheless, these by-products are rich in collagen, keratin, and minerals, being thus promising sources of high-value materials such as bioenergy, biochemical and other biomaterials that could be exploited in various industrial applications. In this paper, the possible utilization of slaughterhouse by-products for the production of various high added value materials is discussed. In this context, the various processes presented provide solutions to more sustainable management of the slaughterhouse industry, contributing to the reduction of environmental degradation via soil and water pollution, the avoidance of space depletion due to landfills, and the development of a green economy.