Conspectus
In meeting the increasing need for clean water in both developing
and developed countries and in rural and urban communities, photothermal
membrane water treatment technologies provide outstanding advantages:
For developing countries and rural communities, by utilizing sunlight,
photothermal membrane water treatment provides inexpensive, convenient,
modular, decentralized, and accessible ways to clean water, which
can reduce the consumption of conventional energy (e.g., electricity,
natural gas) and the cost of clean water production. In developed
countries and urban communities, photothermal membrane water treatment
can improve the energy efficiency during water purification. In these
water purification processes, the light absorption and light-to-heat
conversion of photothermal materials are important factors in determining
the membrane efficacy. Nanomaterials with well-controlled structure
and optical properties can increase the light absorption and photothermal
conversion of newly developed membranes.
This Account introduces
our recent work on developing scalable,
cost-effective, and highly efficient photothermal membranes for four
water purification applications: reverse osmosis (RO), ultrafiltration
(UF), solar steam generation (SSG), and photothermal membrane distillation
(PMD). By utilizing photothermal materials, first, we have demonstrated
how sunlight can be used to improve the membrane’s resistance
to biofouling in RO and UF processes by photothermally induced inactivation
of microorganisms. Second, we have developed novel SSG membranes (i.e.,
interfacial evaporators) that can harvest solar energy, convert it
to localized heat, and generate clean water by evaporation. This desalination
approach is particularly useful and promising for treatment of highly
saline water. These new interfacial evaporators utilized graphene
oxide (GO), reduced graphene oxide (RGO), molybdenum disulfide (MoS2), and polydopamine (PDA). The solar conversion efficiency
and environmental sustainability of the interfacial evaporators were
optimized via (i) novel and versatile bottom-up biofabrication (e.g.,
incorporation of photothermal materials during bacterial nanocellulose
(BNC) growth) and (ii) easy and cost-effective top-down preparation
(e.g., modification of natural wood with photothermal materials).
Third, we have developed membranes for PMD that incorporate photothermal
materials to generate heat under solar irradiation, thus providing
a higher transmembrane temperature difference and higher driving force
for effective vapor transport, making the membrane distillation process
more energy-efficient. Lastly, this Account compares the photothermal
membrane applications, summarizes current challenges for photothermal
membrane applications, and offers future directions to facilitate
the translation of photothermal membranes from the laboratory to large
engineered systems by improving their scalability, stability, and
sustainability.