Colloids have increasingly been used to characterize or mimic many aspects of atomic and molecular systems. With confocal microscopy these colloidal particles can be tracked spatially in three dimensions with great precision over large time scales. This review discusses equilibrium phases such as crystals and liquids, and non-equilibrium phases such as glasses and gels. The phases that form depend strongly on the type of particle interaction that dominates. Hard-sphere-like colloids are the simplest, and interactions such as the attractive depletion force and electrostatic repulsion result in more non-trivial phases which can better model molecular materials. Furthermore, shearing or otherwise externally forcing these colloids while under microscopic observation helps connect the microscopic particle dynamics to the macroscopic flow behaviour. Finally, directions of future research in this field are discussed.
An experimental investigation into the influence of Brownian motion on shear-induced particle migration of monodisperse suspensions of micrometre-sized colloidal particles is presented. The suspension is pumped through a 50 µm × 500 µm rectangular crosssection glass channel. The experiments are characterized chiefly by the sample volume fraction (φ = 0.1 − 0.4), and the flow rate expressed as the Péclet number (Pe = 10 − 400). For each experiment we measure the entrance length, which is the distance from the inlet of the channel required for the concentration profile to develop to its non-uniform steady state. The entrance length increases strongly with increasing Pe for Pe 100, in marked contrast to non-Brownian flows for which the entrance length is flow-rate independent. For larger Pe, the entrance length reaches a constant value which depends on the other experimental parameters. Additionally, the entrance length decreases with increasing φ; this effect is strongest for low φ. Modelling of the migration based on spatial variation of the normal stresses due to the particles captures the primary features observed in the axial evolution over a range of Pe and φ.
We present experimental investigations of the spatial and temporal evolution of particle migration in pressure driven flows of Brownian particle suspensions. Binary suspensions of 1.4 and 3.0 m diameter colloidal particles are pumped through a 50ϫ 500 m 2 rectangular-cross-section capillary tube. Shear rate gradients caused by the resulting parabolic velocity profile drive the particles away from the walls toward the center of the channel, where the shear rate is lowest. The flows are directly imaged using high-speed laser scanning confocal microscopy. Size segregation of the particles is observed. Depending on the conditions, either the large or the small particles enrich the center. We measure the development of the size segregation by tracking the evolution of the cross-stream concentrations of the particles.
The rheology of dense amorphous materials under large shear strain is not fully understood, partly due to the difficulty of directly viewing the microscopic details of such materials. We use a colloidal suspension to simulate amorphous materials and study the shear-induced structural relaxation with fast confocal microscopy. We quantify the plastic rearrangements of the particles in several ways. Each of these measures of plasticity reveals spatially heterogeneous dynamics, with localized regions where many particles are strongly rearranging by these measures. We examine the shapes of these regions and find them to be essentially isotropic, with no alignment in any particular direction. Furthermore, individual particles are equally likely to move in any direction other than the overall bias imposed by the strain.
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