This paper presents a theoretical investigation of the polarization and magnetic sensitivity of the near-ultraviolet (near-UV) solar spectral lines of Fe ii between 250 and 278 nm. In recent years, UV spectropolarimetry has become key to uncovering the magnetism of the upper layers of the solar chromosphere. The unprecedented data obtained by the CLASP2 suborbital space experiment across the Mg ii h and k lines around 280 nm are a clear example of the capabilities of near-UV spectropolarimetry for magnetic field diagnostics throughout the whole solar chromosphere. Recent works have pointed out the possible complementary diagnostic potential of the many Fe ii lines in the unexplored spectral region between 250 and 278 nm, but no quantitative analysis of the polarization and magnetic sensitivity of those spectral lines has been carried out yet. To study the polarization signals in these spectral lines, we create a comprehensive atomic model including all the atomic transitions resulting in strong spectral lines. We then study the magnetic sensitivity of the linear and circular polarization profiles in a semiempirical model representative of the quiet Sun. We present a selection of Fe ii spectral lines with significant linear and circular polarization signals and evaluate their diagnostic capabilities by studying their formation heights and magnetic sensitivity through the action of the Hanle and Zeeman effects. We conclude that when combined with the CLASP2 spectral region these Fe ii lines are of interest for the inference of magnetic fields throughout the solar chromosphere, up to near the base of the corona.
The Mg ii h and k lines are among the strongest in the near-ultraviolet solar spectrum and their line core originates in the upper chromosphere, just below the transition region. Consequently, they have become one of the main targets for investigating the magnetism of the upper solar atmosphere. The recent Chromospheric Layer Spectropolarimeter (CLASP2) mission obtained unprecedented spectropolarimetric data on these lines in an active region plage, which have already been used to infer the longitudinal component of the magnetic field by applying the weak-field approximation. In this paper, we aim at improving our understanding of the diagnostic capabilities of these lines by studying the emergent Stokes profiles resulting from radiative transfer calculations in a radiative magnetohydrodynamic time-dependent model representative of a solar plage. To this end, we create a synthetic observation with temporal and spatial resolutions similar to those of CLASP2. We find strong asymmetries in the synthetic profiles of circular polarization, which considerably complicate the application of the weak-field approximation. We demonstrate that the selective application of the weak-field approximation to fit different spectral regions in the profile allows us to retrieve information about the longitudinal component of the magnetic field in different regions of the model atmosphere, even when the circular polarization profiles are not antisymmetric and are formed in the presence of strong velocity and magnetic field gradients.
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