Rayleigh–Taylor-instability (RTI) induced flow and mixing are of great importance in both nature and engineering scenarios. To capture the underpinning physics, tracers are introduced to make a supplement to discrete Boltzmann simulation of compressible RTI flows. By marking two types of tracers with different colors, the tracer distribution provides a clear boundary of two fluids during the evolution. Fine structures of RTI flow and thermodynamic non-equilibrium behavior around the interface in a miscible two-fluid system are delineated. Distribution of tracers in their velocity phase space makes a charming pattern showing quite dense information on the flow behavior, which opens a new perspective for analyzing and accessing significantly deep insights into the flow system. RTI mixing is further investigated via tracer-defined local mixedness. The appearance of Kelvin–Helmholtz instability is quantitatively captured by the abrupt increase in mixedness averaged along the direction of acceleration. The role of compressibility and viscosity on mixing are investigated separately, both of which show a two-stage effect. The underlying mechanism of the two-stage effect is interpreted as the development of large structures at the initial stage and the generation of small structures at the late stage. At the late stage, for a fixed time, a saturation phenomenon of viscosity is found that a further increase in viscosity cannot lead to an evident decline in mixedness. The mixing statues of heavy and light fluids are not synchronous and the mixing of an RTI system is heterogeneous. The results are helpful for understanding the mechanism of flow and mixing induced by RTI.
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