Assemblies of inorganic or glassy particles are typically brittle and cannot sustain even moderate deformations. This restricts the use of such materials to applications where they do not experience significant loading or deformation. Here, we demonstrate a general strategy to create centimeter-size macroporous monoliths, composed primarily (>90 wt %) of colloidal particles, that recover elastically after compression to about one-tenth their original size. We employ ice templating of an aqueous dispersion of particles, polymer, and crosslinker such that cross-linking happens in the frozen state. This method yields elastic composite scaffolds for starting materials ranging from nanoparticles to micron-sized dispersions of inorganics or glassy lattices. The mechanical response of the monoliths is also qualitatively independent of polymer type, molecular weight, and even cross-linking chemistry. Our results suggest that the monolith mechanical properties arise from the formation of a unique hybrid microstructure, generated by cross-linking the polymer during ice templating. Particles that comprise the scaffold walls are connected by a cross-linked polymeric mesh. This microstructure results in soft monoliths, with moduli ∼O (10 4 Pa), despite the very high particle content in their walls. A remarkable consequence of this microstructure is that the monolith mechanical response is entropic in origin: the modulus of these scaffolds increases with temperature over a range of 140 K. We show that interparticle connections formed by cross-linking during ice templating determine the monolith modulus and also allow relative motion between connected particles, resulting in entropic elasticity.
Drilling is one of the most important method for hole making in composite materials. Drilling of polymer matrix composites causes substantial damage around the drilled hole. Damage free holes can be made using modified drill geometry. The present research investigation focuses on the drill geometry as candidate parameter that influence drilling forces and drilling-induced damage. The four different drill geometries (solid and hollow in shape) are used for drilling in composite materials. The cutting mechanism of these drill geometries is substantially different, and therefore influences the drilling-induced damage. The experimental results suggest a strong relationship between the drill point geometry and the drilling-induced damage.
A modified point stress criterion for predicting the notched strength of glass fibre and carbon fibre laminated composites containing through the thickness centrally located circular or elliptical hole or a center crack is presented here. The effects of hole size and specimen width on the fracture behaviour of several woven fabric composite plates are presented here. It is shown that in the point stress criterion the characteristic length (do) depends on the hole size as well as width of the plate. The analytical based results are in good agreement with existing test results.
The fiber reinforced plastics (FRPs) are being used widely in the most diverse applications ranging from the aerospace to the sports goods industry. Drilling in particular is important to facilitate the assembly operations of structurally intricate composite products. The drilling of holes in FRPs leads to drilling induced damage which is an important research area. The researchers worldwide have tried to minimize the damage by optimizing the operating variables, and tool designs as well as by developing unconventional methods of hole making. Most of the work done so far has been experimental in nature with little or no focus on numerical simulation of the drilling behavior of FRPs. In the present research endeavor, a finite element model has been developed to investigate the drilling induced damage of FRP laminates
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