The use of inexpensive K2S2O8 in water at room temperature for synthesis of bis(indolyl)methanes (BIMs) from simple indoles and alcohols is reported. The key step involves the conversion of alcohols...
A base‐free, intramolecular Sonogashira reaction‐based general approach has been established for the diversity‐oriented synthesis (DOS) of fused bi‐ and tricyclic systems containing benzannulated, 10‐ to 13‐membered chiral macrocycles embedded in carbohydrate templates. Macrocycles with different ring sizes have been prepared by pre‐designing the chiral building blocks. Base‐sensitive groups like acetyl and TBDPS survived the reaction conditions.
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