Resumo: Neste estudo, quatro misturas de PEBD pós-consumo com gasóleo pesado da Bacia de Campos, em diferentes proporções, foram submetidas à pirólise em atmosfera inerte a 550 °C. Os líquidos pirolíticos foram caracterizados por cromatografia em fase gasosa acoplada à espectrometria de massas (CG/EM). A pirólise do gasóleo puro forneceu elevado teor de resíduo e apenas 4% hidrocarbonetos na faixa do óleo diesel. Por outro lado, a pirólise da mistura de gasóleo com PEBD (na proporção 1/0,5 em m/m) forneceu 20% de hidrocarbonetos leves com elevada produção de óleo pirolítico (96%). Desta forma, pode-se concluir que a pirólise de resíduos plásticos com gasóleo pesado pode ser uma tecnologia promissora não apenas para aumentar a formação de hidrocarbonetos leves derivados de gasóleo pesado como também para o reaproveitamento de resíduos plásticos. Palavras-chave: Co-pirólise, resíduo plástico, polietileno. Co-pirolysis of Polyethylene Waste with the Campos Bacia Heavy OilAbstract: In this study, four mixtures of LDPE post consumer with heavy gas from the Campos Basin, in different proportions, were subjected to pyrolysis in an inert atmosphere at 550 °C. The pyrolytic liquids were characterized by gas chromatography coupled to mass spectrometry (GC/MS). Pyrolysis of pure diesel supplied large amounts of waste oil and only 4% in the range of diesel. On the other hand, the pyrolysis of LDPE mixture of diesel (at the ratio 1/0,5 m/m) provided 20% of light hydrocarbons with high production of pyrolytic oil (96%). The formation of high levels of paraffins and olefins in the range of diesel oil during the co-pyrolysis suggests a promising technology for recycling of plastic waste.
In this work the process of co-pyrolysis of polyethylene plastic residue was carried through with petroleum, in a temperature of 550°C. First, the polyethylene samples and petroleum had been submitted the thermal co-pyrolysis in inert atmosphere. Later they had been evaluated the efficiency of the process with variation of the amount of polyethylene residue added to the petroleum. The generated pyrolytic liquids had been characterized by modified gaseous chromatography, with the objective to evaluate the generation of fractions in the band of the distillation of diesel. It can be observed that the increase of the amount of PE in the half reactional favors the reduction of the income of pyrolytic liquid and the increase of the amount of generate solid. The results show that plastic residue co-pyrolysys is a potential method for chemical recycling of plastic products.
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