The present study is aimed to explore the pollution potential of automobile service station wastewater and to treat the same. The wastewater samples were collected from different servicing points of a typical automobile garage and then characterized for parameters like pH, Total solids, Total Suspended Solids, Chemical Oxygen Demand (COD) as well as Oil and Grease. A composite sample was also prepared on the basis of wastewater generation pattern. The characterization results revealed that oil and grease and COD were two major pollution parameters of concern. The composite oily wastewater was firstly treated using coagulants like alum, FeSO 4 and CaCl 2. The results showed that removal is feasible for initial oil concentration in the range of 300-600 mg/L for the alum dose of 100-400 mg/L, alum + bentonite dose of 20-250 mg/L and FeSO 4 dose of 50-200 mg/L. Subsequently, treatment of the composite wastewater with acclimated suspended biomass (activated sludge) resulted about 18-68% removal efficiency for initial oil and grease concentration of 300-600 mg/L under the batch period of 18-30 hours.
Anaerobic digestion (AD) of the organic fraction of municipal solid waste (OFMSW) has gained great interest in the last few decades. Presently, among the various municipal solid waste management (MSWM) techniques, such as sanitary land-filling, aerobic or anaerobic composting, and thermal incineration, AD is being considered as the most techno-economically viable method owing to its many advantages. AD not only serves to efficiently manage and treat an enormous quantity of OFMSW but also acts as a convenient source of non-conventional energy. The methane generated via AD of OFMSW serves as a potent substitute for fossil-based fuels. Given the current global energy crisis, this technology may be a welcome boost to the global energy demand. In this review an attempt has been made to provide a comprehensive understanding of: (i) the origin and scope of AD of OFMSW; (ii) the potential of AD for OFMSW stabilization; (iii) various pilot and bench-scale studies conducted hitherto; (iv) the process design aspects of AD of OFMSW; (v) the potential of energy recovery from AD of OFMSW; and (vi) the past experiences of AD of OFMSW. This review also delves into the critical issues that govern the process of AD in stabilizing OFMSW. In addition, the compatibility of AD for MSWM in the Indian scenario compared to other classical methodologies, such as landfilling, composting, thermal incineration, and pyrolysis or gasification, is highlighted. An overview of the overall future prospect of AD of OFMSW is discussed.
Nitrification of ammonium nitrogen (NH4+-N)-bearing synthetic wastewater was performed in a batch-activated sludge reactor by varying the initial ammonium nitrogen concentration up to 400 mg/L at a pH of 8.1 ± 0.2 and temperature of 36 ± 2 °C for developing the process kinetics using acclimatised biomass. Maximum ammonium nitrogen removal efficiency of 98.3% was achieved with initial ammonium nitrogen and mixed liquor suspended solids concentration of 235 mg/L and 2,180 mg/L, respectively, at 48 h batch period. Based on the experimental results, kinetic constants for ammonia nitrogen removal following Monod's approach were obtained as maximum substrate removal rate coefficient = 0.057 per day, yield coefficient = 0.336 mg volatile suspended solids/mg ammonium nitrogen, half velocity constant = 12.95 mg NH4+-N/L and endogenous decay constant = 0.02 per day. Nitrification is a consecutive reaction with ammonium oxidation as the first step followed by nitrite oxidation. The overall rate of nitrite and nitrate formation was observed to be 1.44 per day and 0.34 per day, respectively.
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