The assessment of environmental radioactivity much relies on radionuclide content in soil. This stems from the significant contribution of soil to both external and internal exposure to ionising radiation via direct emission of gamma radiation and soil-to-plant radionuclide transfer, respectively. This motivated us to carry out a systematic research on the radioactivity of soil in Croatia to obtain relevant data that can be used as a basis for understanding the related effects of geomorphological, biogeographical, and climatological properties of the environment. We collected samples of the surface layer of uncultivated soil (0–10 cm) at 138 sites from all over the country and measured them for radionuclide activity concentrations by means of high-resolution gamma-ray spectrometry. This resulted in radioactivity maps containing data on activity concentrations of representative radionuclides in the environment. In this paper, which is the first in our two-part presentation, we focus on the naturally occurring 232Th and 238U decay chains and their correlations with the diversity of Croatian regions. For both of the chains, activity concentrations were the highest in the Dinaric region, the lowest in the Pannonian region, and intermediate in the Adriatic region. Relatively high concentrations of 226Ra in the soil of the Dinaric region implied a possibility of an enhanced emanation of its progeny 222Rn into the air. Activity concentrations of 210Pb were additionally elevated in areas with dense vegetation, most probably due to an atmospheric deposition of airborne 210Pb onto the surface of plants and their eventual decomposition on the ground.
Phosphogypsum (PG) is a waste by-product (residue) originating from the production of phosphoric acid and phosphate fertilisers. PG contains chemical and radioactive impurities, which is why it is mostly stockpiled in controlled areas. Worldwide, only about 15 % of PG is recycled or reused. Today, policies and business strategies prioritise sustainable development through circular economy, which certainly includes PG. This provides new opportunities for Croatia to manage its PG and make an effort to use it as an additive in different industries, such as agriculture and construction. Due to its chemical and radiological properties, PG can potentially cause problems for the environment and human health. Hence, before using PG, detailed knowledge of potential hazards is necessary to protect people and the environment. The aim of this review is to summarise available data on Croatian PG, compare them with other countries, and to identify knowledge gaps and the lack of data on potential hazardous substances in PG in order to assess the opportunities of using PG in Croatia.
In situ gamma ray spectrometry was developed to quickly measure large areas of land following nuclear accidents. However, a proper calibration of detectors for in situ measurements is a long and complicated process. One tool designed to make this calibration quick is the InSiCal software. We compared 5,000 s in situ measurements with two different HPGe detectors calibrated using the InSiCal software and laboratory measurements of samples collected at the same locations. Our findings suggest that in situ gamma spectrometry using InSiCal software can provide reasonably accurate data, but some improvements are needed.
Fly bioash (FBA) as a by-product of biomass-fuelled facilities exhibits alkaline properties and is enriched with phytonutrients, thereby offering the potential to effectively ameliorate acidic and nutrient-deficient soils. However, concerns about health risks due to a potential FBA radioactive contamination are still not well studied, notably under field conditions. This study examined pH changes and concentrations of natural (238U, 232Th, 226Ra, 40K) and anthropogenic (137Cs) radionuclides after application of very alkaline (pH > 12) FBA in: (i) highly acid (pHKCl = 4.1) Luvisol and (ii) sunflower (Helianthus annuus L.) seeds, grown in organic farming and rain-fed conditions. FBA (originated from a modern cogeneration, fuelled on certified deciduous forest wood chips) was applied at increasing doses; 0, 4.5, 8.6, 13, and 17.2 t/ha. After 54 months of application, FBA significantly increased soil pHKCl by up to 1.8 unit and the seed yield by 15%, compared with no amended Control, without compromising soil electrical conductivity (salinity). The activity concentrations (Ac) of all observed radionuclides, measured using high-resolution gamma-ray spectrometry, were not altered under FBA application, neither in the surface (0–30 cm) Luvisol horizon nor in the sunflower seed. Moreover, the Ac of 238U, 232Th, and 137Cs in the seed were below detection limit, whereas the Ac of 40K and 226Ra were lower by up to 2.6 and 61 times, respectively, than their corresponding Ac in the soil treatments. The radiological footprint of FBA exhibited lower Ac for most of the observed radionuclides compared with both (i) Croatian non-arable topsoils (with reductions of 238U 3.6 times, 232Th 1.8 times, 226Ra 1.7 times, and 137Cs 1.5 times) and (ii) widely used mineral N/P/K fertilisers in conventional agroecosystems (with reductions of 238U 12.5 times; 226Ra 1.3 times, and 40K 2.4 times). Our findings provide evidence that the application of FBA as a soil conditioner does not pose radiological health or environmental risks, contributing to more sustainable agri-food production and circular bioeconomy. However, it is essential to conduct further studies to comprehensively investigate the effects of FBA application on soil and crop quality across diverse environmental conditions and extended spatiotemporal scales.
We took samples of uncultivated soil from the surface layer (0–10 cm) at 138 sites from all over Croatia and measured their radionuclide activity concentrations with high-resolution gamma-ray spectrometry. This second part of our report brings the results on 40K and 137Cs to complement those on the 232Th and 238U decay chains addressed in the first part. Together they give the most complete picture of radioactivity of Croatian soil so far. Activity concentrations of 40K were the highest in the Pannonian region, and there was an opposite trend for 137Cs. We found that the concentrations of 137Cs tended to increase with altitude, annual precipitation, and vegetation density. The concentration ratio of 137Cs and K in soil, which indicates the potential for 137Cs entering food chains via uptake by plants, was the lowest in agriculturally important areas in the east of the Pannonian region. In addition, we used the obtained results on activity concentrations to calculate the related absorbed dose rate as a measure of external exposure to ionising radiation from soil. The sum of the absorbed dose rates for naturally occurring radionuclides and 137Cs showed that external exposure was generally the highest in the Dinaric region and Istrian Peninsula.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.
hi@scite.ai
10624 S. Eastern Ave., Ste. A-614
Henderson, NV 89052, USA
Copyright © 2024 scite LLC. All rights reserved.
Made with 💙 for researchers
Part of the Research Solutions Family.