Inverse nematic emulsions in which surfactant-coated water droplets are dispersed in a nematic host fluid have distinctive properties that set them apart from dispersions of two isotropic fluids or of nematic droplets in an isotropic fluid. We present a comprehensive theoretical study of the distortions produced in the nematic host by the dispersed droplets and of solvent mediated dipolar interactions between droplets that lead to their experimentally observed chaining. A single droplet in a nematic host acts like a macroscopic hedgehog defect. Global boundary conditions force the nucleation of compensating topological defects in the nematic host. Using variational techniques, we show that in the lowest energy configuration, a single water droplet draws a single hedgehog out of the nematic host to form a tightly bound dipole. Configurations in which the water droplet is encircled by a disclination ring have higher energy. The droplet-dipole induces distortions in the nematic host that lead to an effective dipole-dipole interaction between droplets and hence to chaining.
1In thin films of smectic-C liquid crystals, localized regions containing additional smectic layers form circular inclusions that carry a topological charge. Such inclusions nucleate a companion topological defect. These inclusion-defect pairs are modeled as topological dipoles within the context of a one-coupling constant approximation to the 2D Frank free energy. Deviations of the dipole direction from a preferred orientation cause the dipoles to acquire a logarithmic charge. Thermal fluctuations of the dipole direction are calculated and found to be large, scaling as the logarithm of the system size. In addition to dipole-dipole interactions arising from the topological charges, we also find that the thermal fluctuations of the dipole directions are coupled through a preference for global charge neutrality of the logarithmic charges.2
Finite domains of a Langmuir monolayer in a phase with tilted molecules can be modeled by a simple elastic free energy of an XY order parameter with isotropic and anisotropic line tension terms. The domains can and often do contain nontrivial textures, which in turn influence the shape of the domains. Herein we investigate the properties of a simplified isotropic model with a single elastic constant. For circular domains a first-order phase transition is found between two distinct textures: an exterior defect (or "virtual boojum") texture, and an interior defect texture. Starting with a circular domain and either of these two textures as a ground state, we find shape instabilities develop that depend on the elastic constants and line tensions in the simplified model. In both cases a necessary but not sufficient condition for the onset of shape instabilities is the possibility for a local negative effective line tension to develop from the anisotropic line tension term.
A radiation-resistant plastic scintillator has been developed to withstand the high radiation dose regions that will be present in the proposed SSC and LHC accelerators. The base is a highly transparent and radiation resistant polysiloxane plastic. This has been doped with a variety of radiation resistant fluors. The resultant scintillators have been to shown to be highly resistant to @CO gamma radiation for doses of 10 megarad.
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