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Anthropogenic activities contribute to the release of a wide variety of volatile organic compounds (VOC) into microenvironments. Developing and implementing new air sampling technologies that allow for the characterization of exposures to VOC can be useful for evaluating environmental and health concerns arising from such occurrences. A novel air sampler based on the use of a capillary flow controller connected to evacuated canisters (300 mL, 1 and 6 L) was designed and tested. The capillary tube, used to control the flow of air, is a variation on a sharp-edge orifice flow controller. It essentially controls the velocity of the fluid (air) as a function of the properties of the fluid, tube diameter and length. A model to predict flow rate in this dynamic system was developed. The mathematical model presented here was developed using the Hagen-Poiseuille equation and the ideal gas law to predict flow into the canisters used to sample for long periods of time. The Hagen-Poiseuille equation shows the relationship between flow rate, pressure gradient, capillary resistance, fluid viscosity, capillary length and diameter. The flow rates evaluated were extremely low, ranging from 0.05 to 1 mL min(-1). The model was compared with experimental results and was shown to overestimate the flow rate. Empirical equations were developed to more accurately predict flow for the 300 mL, 1 and 6 L canisters used for sampling periods ranging from several hours to one month. The theoretical and observed flow rates for different capillary geometries were evaluated. Each capillary flow controller geometry that was tested was found to generate very reproducible results, RSD < 2%. Also, the empirical formulas developed to predict flow rate given a specified diameter and capillary length were found to predict flow rate within 6% of the experimental data. The samplers were exposed to a variety of airborne vapors that allowed for comparison of the effectiveness of capillary flow controllers to sorbent samplers and to an online gas chromatograph. The capillary flow controller was found to exceed the performance of the sorbent samplers in this comparison.

Student participants who were high vs. low on Altemeyer's (1996) Right‐Wing Authoritarianism (RWA) scale read background information and observed a videotaped interview concerning a schizophrenic woman who ostensibly killed her 2 young children in response to what she perceived as divine command. The woman now was functioning normally in response to medical treatment. High RWAs recommended harsher sentencing and expressed less sympathy than did low RWAs. High RWAs also evinced more facial electromyographic activity from the corrugator brow (i.e., frown) muscle while observing the interview than did low RWAs and gave the woman lower ratings on the Affective Attitudes Scale (Crites, Fabrigar, & Petty, 1994).

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A two-dimensional (one space and time) scalar adaptation of the proper orthogonal decomposition was applied to streamwise velocity data obtained in a lobed mixer flowfield, using a rake of 15 single-component hot wires. Through the application of the proper orthogonal decomposition, the amount of streamwise turbulent kinetic energy contained in the various proper orthogonal modes was examined for two different downstream locations (z/h = 2.6 and 3.9). The large eddy or dominant mode was shown to have a measurable decrease in the relative streamwise component of the kinetic energy between these two downstream locations. This indicates that the large eddy, as defined by the proper orthogonal decomposition, breaks down, and the flow becomes more homogeneous. A pseudoflow visualization technique was then employed to help visualize this process.