We determine the distribution of two trivalent ions Fe(3+) and La(3+) next to two different amphiphilic charged interfaces as ions or complexes, consisting of the phosphate lipid dihexadecyl phosphate (DHDP) and the fatty acid arachidic acid (AA). These amphiphiles provide a wide range of pK(a) values, from 2.1 (DHDP) to 5.1 (AA), thus allowing manipulation of the surface charge over extremely low pH (pH ∼1 or larger), and the two ions provide two limiting cases of specificity for the amphiphiles. We find that La(3+) distribution is mostly sensitive to the surface charge, whereas the Fe(3+) binding depends on its character in the solution and is highly specific, as indicated by the crucial role played by iron complexes (Fe(OH)(3) or Fe(OH)(2+)) forming covalent bonds even for an uncharged interface. The implications of the results to other ions and/or amphiphilic interfaces are also discussed.
Rydberg atoms, with one highly-excited, nearly-ionized electron, have extreme sensitivity to electric fields, including microwave fields ranging from 100 MHz to over 1 THz. Here we show that room-temperature Rydberg atoms can be used as sensitive, high bandwidth, microwave communication antennas. We demonstrate near photon-shot-noise limited readout of data encoded in amplitude-modulated 17 GHz microwaves, using an electromagnetically-induced-transparency (EIT) probing scheme. We measure a photon-shot-noise limited channel capacity of up to 8.2 Mbit s −1 and implement an 8-state phase-shift-keying digital communication protocol. The bandwidth of the EIT probing scheme is found to be limited by the available coupling laser power and the natural linewidth of the rubidium D2 transition. We discuss how atomic communications receivers offer several opportunities to surpass the capabilities of classical antennas.
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