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Large quantities of microscopic red, green, and blue light-emitting diodes (LEDs) made of crystalline inorganic semiconductor materials micro-transfer printed in large quantities onto rigid or flexible substrates form monochrome and color displays having a wide range of sizes and interesting properties. Transfer-printed micro-LED displays promise excellent environmental robustness, brightness, spatial resolution, and efficiency. Passive-matrix and active-matrix inorganic LED displays were constructed, operated, and their attributes measured. Tests demonstrate that inorganic micro-LED displays have outstanding color, viewing angle, and transparency. Yield improvement techniques include redundancy, physical repair, and electronic correction. Micro-transfer printing enables revolutionary manufacturing strategies in which microscale LEDs are first assembled into miniaturized micro-system "light engines," and then micro-transfer printed and interconnected directly to metallized large-format panels. This paper reviews micro-transfer printing technology for micro-LED displays. FIGURE 3 -(A) Schematic illustration of a micro-transfer stamp that is rigid in horizontal directions and compliant in the vertical dimension. (B) Photograph of a stamp on a 225 × 225 mm glass back. (C) SEM of the stamp posts.FIGURE 4 -Photograph of a 50 × 50 mm stamp silicon master (A) and elastomer stamp (B). The stamp has an array of 250 by 250 posts on a 200-micron pitch with 62,500 posts. Journal of the SID 25/10, 2017 591 FIGURE 9 -Micrographs of an array of microscopic inorganic light-emitting diodes microtransfer printed to a metal-coated substrate (left) and emitting red light (right). The anodes are connected in common with a transparent aluminum zinc oxide anode.

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Rapid synthesis of ultralong silver nanowires (AgNWs) has been obtained using a one-pot polyol-mediated synthetic procedure. The AgNWs have been prepared from the base materials in less than one hour with nanowire lengths reaching 195 μm, which represents the quickest synthesis and one of the highest reported aspect ratios to date. These results have been achieved through a joint analysis of all reaction parameters, which represents a clear progress beyond the state of the art. Dispersions of the AgNWs have been used to prepare thin, flexible, transparent and conducting films using spray coating. Due to the higher aspect ratio, an improved electrical percolation network is observed. This allows a low sheet resistance (RS = 20.2 Ω/sq), whilst maintaining high optical film transparency (T = 94.7%), driving to the highest reported figure-of-merit (FoM = 338). Owing to the light-scattering influence of the AgNWs, the density of the AgNW network can also be varied to enable controllability of the optical haze through the sample. Based on the identification of the optimal haze value, organic photovoltaics (OPVs) have been fabricated using the AgNWs as the transparent electrode and have been benchmarked against indium tin oxide (ITO) electrodes. Overall, the performance of OPVs made using AgNWs sees a small decrease in power conversion efficiency (PCE), primarily due to a fall in open-circuit voltage (50 mV). This work indicates that AgNWs can provide a low cost, rapid and roll-to-roll compatible alternative to ITO in OPVs, with only a small compromise in PCE needed.

Macroporous monolithic cryogels made from poly(vinyl alcohol) (PVA) with degree of saponification 87.7% have been prepared using a crosslinking reaction with glutaraldehyde under acidic conditions at subzero temperatures. The porous structure of the monolithic cryogels from PVA (cryoPVA), analyzed using optical microscopy, scanning electron microscopy, and environmental scanning electron microscopy, revealed interconnected macropores up to 150 m in size with a noticeable microporosity of the gel walls. Differential scanning calorimetry measurement showed that more than 90% of the water in the cryoPVA monoliths was freezable water, while the amount of polymer bound water increased with increase in the polymer concentration in the cryoPVA sample. The swelling degree of cryoPVA depended on concentration of polymer in the initial reaction mixture and degree of crosslinking. The cryoPVA monoliths were elastic and spongy-like materials that can be dried, stored in dried state, and re-swelled when required. Derivatization of hydroxyl-groups of the cryoPVA monolith allowed incorporation of required functionality. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1057-1066, 200