Metasurfaces are ultrathin, two-dimensional arrays of subwavelength resonators that have been demonstrated to control the flow of light in ways that are otherwise unattainable with natural materials. These arrays are typically composed of metallic Ag or Au nanostructures shaped like split rings, nanowire pairs or nanorods (commonly referred to as meta-atoms) that are arranged to produce a collective optical response spanning an impressive range of properties, from the perfect absorption of incident light to superresolution imaging. However, metasurfaces pose major challenges in their fabrication over large areas, which can be prohibitively expensive and time consuming using conventional nanolithography techniques. Here we show that differently shaped colloidal nanocrystals can be organized into metasurface architectures using robust, scalable assembly methods. These metasurfaces exhibit extreme in-plane electromagnetic coupling that is strongly dependent on nanocrystal size, shape and spacing. Colloidal metasurfaces that display near-ideal electromagnetic absorbance can be tuned from the visible into the mid-infrared wavelengths.

Self-organized metal nanoparticles often possess assembly defects that can have a profound impact on the optical properties of the resulting nanoparticle assembly. Modeling these defects and evaluating their optical outcomes can provide a better understanding of how to design the assembly process and can evaluate the quality of the resulting materials. Here, we use finite element methods to examine the fabrication of bowtie nanoantenna, a commonly sought-after plasmonic structure with resonances in the visible and near-infrared wavelengths, through the self-assembly of colloidal triangular Ag nanoprisms. We model perfect and defective antenna structures and examine the effects of commonly observed assembly defects such as imperfect nanoprism shapes, off-axis antenna structures, and trimer or tetramer formation. We also evaluate the ability to fabricate antenna structures that possess comparable structural parameters (e.g., thickness, gap distance) to top-down lithographic techniques. We find that structural defects in self-assembled bowties can shift the resonant wavelength of the antenna by as much as 200 nm. Our models also indicate that self-assembled bowties possess high defect tolerances with respect to near-field enhancement, suggesting that they are viable structures for nanophotonic and nanoplasmonic applications.

We demonstrate that polymer-grafted metal nanoparticles of various shapes and dimensions self-assemble into arrays of string-like superstructures upon phase separation within a matrix polymer. Interparticle orientation within these nanocomposites can be dictated by the chain length of the grafted polymer.

We show that the optical design of strong-cavity, top-emitting (SCTE) OLEDs is limited by tradeoffs between optical efficiency and color-shift. Color correction technologies can be leveraged to overcome these tradeoffs, opening the design space for SCTE OLEDs.