In many Countries, small communities are required to treat wastewater discharges to increasing standards of lesser environmental impacts, but must achieve that goal at locally sustainable costs. While biological membrane treatment (membrane bio-reactors (MBRs)) is quickly becoming the industry standard for centralized wastewater treatment plants, and would also be ideally suited also for small plants potentially subject to relatively large hydraulic load variations, its investment and operating costs are usually high for that class of applications. Consequently, small treatment plants are generally configured as anoxic or aerated biological tanks with little sedimentation, making them quite susceptible to hydraulic loads transient and sludge quality changes. As an alternative, Constructed Wetlands Systems (CWSs) are gradually and successfully being introduced in many Countries. CWSs are designed to utilise the natural functions of wetland vegetation, soils and their microbiological populations to treat wastewater. Pretreatment occurs by filtration and settling, followed by bacterial decomposition in a natural-looking lined marsh. A new technology, a new type of membrane-like aerobic reactor initially designed for the degradation of hydrocarbon-derived groundwater contaminants, was recently tested for treating domestic, with performance similar to that of MBRs. Examples from the above applications are illustrated and compared in this paper. The paper also discusses merits and drawbacks of the various illustrated technologies, in view of their sustainability potential, and according to the new development paradigms for urban water systems, that encourage the development of local water-cycle clusters with local reuse and recycle of the resource, and possible local recovery of energy and/or materials.

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Application of microbial fuel cells (MFCs) to wastewater treatment for direct recovery of electric energy appears to provide a potentially attractive alternative to traditional treatment processes, in an optic of costs reduction, and tapping of sustainable energy sources that characterizes current trends in technology. This work focuses on a laboratory-scale, air-cathode, and single-chamber MFC, with internal volume of 6.9 L, operating in batch mode. The MFC was fed with different types of substrates. This study evaluates the MFC behaviour, in terms of organic matter removal efficiency, which reached 86% (on average) with a hydraulic retention time of 150 hours. The MFC produced an average power density of 13.2 mW/m3, with a Coulombic efficiency ranging from 0.8 to 1.9%. The amount of data collected allowed an accurate analysis of the repeatability of MFC electrochemical behaviour, with regards to both COD removal kinetics and electric energy production.

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Development of renewable energy sources, efficient industrial processes, energy/chemicals recovery from wastes are research issues that are quite contemporary. Bioelectrochemical processes represent an eco-innovative technology for energy and resources recovery from both domestic and industrial wastewaters. The current study was conducted to: (i) assess bioelectrochemical treatability of industrial (dairy) wastewater by microbial fuel cells (MFCs); (ii) determine the effects of the applied organic loading rate (OLR) on MFC performance; (iii) identify factors responsible for reactor energy recovery losses (i.e. overpotentials). For this purpose, an MFC was built and continuously operated for 72 days, during which the anodic chamber was fed with dairy wastewater and the cathodic chamber with an aerated mineral solution. The study demonstrated that industrial effluents from agrifood facilities can be treated by bioelectrochemical systems (BESs) with >85% (average) organic matter removal, recovering power at an observed maximum density of 27 W m. Outcomes were better than in previous (shorter) analogous experiences, and demonstrate that this type of process could be successfully used for dairy wastewater with several advantages.