The motion of soft-glassy materials (SGM) in a confined geometry is strongly impacted by surface roughness. However, the effect of the spatial distribution of the roughness remains poorly understood from a more quantitative viewpoint. Here we present a comprehensive study of concentrated emulsions flowing in microfluidic channels, one wall of which is patterned with micron-size equally spaced grooves oriented perpendicularly to the flow direction. We show that roughness-induced fluidization can be quantitatively tailored by systematically changing both the width and separation of the grooves. We find that a simple scaling law describes such fluidization as a function of the density of grooves, suggesting common scenarios for droplet trapping and release. Numerical simulations confirm these views and are used to elucidate the relation between fluidization and the rate of plastic rearrangements. Controlling the slip and flow of soft-glassy materials (SGM) at the microscale is crucial for food and pharmaceutical processing, and for micro-manufacturing [1][2][3][4]. SGM include concentrated emulsions, gels, foams, pastes, and exhibit a complex, non-linear rheology [5][6][7]: they behave like elastic solids unless a stress large enough, known as the yield stress σ Y , is applied. Above σ Y SGM flow like non-Newtonian liquids. This solidto-liquid transition and the corresponding flowing properties have been widely studied [8], but still pose a series of challenging questions, relevant both for applications [9][10][11] and for a better understanding of the statistical mechanics of SGM [12][13][14][15][16][17][18][19][20]. Recent studies [21][22][23][24][25][26][27][28][29] showed that their flow bahavior is characterized by "nonlocality" [21,22], meaning that the relation between the local stress σ and the local shear rateγ cannot be explained with a unique master curve. This non-local behaviour depends on both confinement and surface roughness [22,25,26], and it is ascribed to the presence of plastic rearrangements [21,22], i.e. topological changes in the micro-structural configurations. These take place whenever the material cannot sustain the accumulated stress, then it undergoes an irreversible deformation and releases the excess stress in the form of elastic waves. The range of such perturbation introduces a new length, named "cooperativity length" ξ [21], which is typically on the order of a few diameters of micro-structural constituents (i.e. droplets for emulsions [21,22], bubbles for foams [27,28], blobs for gels [29], etc). Although the cooperativity length becomes relevant at the jamming point of SGM [30], it has been sharply argued that ξ is fundamentally different from the characteristic legnth that describes dynamical heterogeneities involved in spontaneous fluctuations [31][32][33]. Recently, many theoretical studies have been put forward in the recent years to account for these non-local effects [12,[15][16][17]20]. One of them, the kinetic elastoplastic (KEP) model [16], explores the effects of coopera...
We have studied the motion of drops on inclined liquid-impregnated surfaces (LISs) subject to vertical vibrations. The liquid drops comprise distilled water and different aqueous solutions of glycerol of increasing viscosity. The use of weak pinning LISs strongly affects the dynamical phase diagram. First of all, there is no trace of the dominant static region at low oscillating amplitudes reported for oscillating solid surfaces characterized by contact angle hysteresis. On the contrary, at sufficiently low oscillating amplitudes, the drops always move downwards with a velocity that depends only on the drop viscosity. Further increasing the oscillating amplitude may drive the drop upwards against gravity, as reported for dry surfaces. The use of more viscous drops widens this climbing region. Arguably, the main novelty of this work concerns the observation of two distinct descending regimes where the downhill speed differs by a factor of five or more. Fast-rate videos show that the evolution of the drop profile is diverse in the two regimes, likely because the vertical oscillations reduce the effect of the oil meniscus surrounding the drop at high accelerations.
Fluidization of soft glassy materials (SGMs) in microfluidic channels is affected by the wall roughness in the form of microtexturing. When SGMs flow across microgrooves, their constituents are likely trapped within the grooves' gap, and the way they are released locally modifies the fluidization close to the walls. By leveraging a suitable combination of experiments and numerical simulations on concentrated emulsions (a model SGM), we quantitatively report the existence of two physically different scenarios. When the gap is large compared to the droplets in the emulsion, the droplets hit the solid obstacles and easily escape scrambling with their neighbors. Conversely, as the gap spacing is reduced, droplets get trapped inside, creating a "soft roughness" layer, i.e. a complementary series of deformable posts from which overlying droplets are in turn released. In both cases, the induced fluidization scales with the grooves' density, although with a reduced prefactor for narrow gaps, accounting for the softness of the roughness. Both scenarios are also well distinguished via the statistics of the droplets displacement field close to the walls, with large deviations induced by the surface roughness, depending on its stiffness.
The motion of partially wetting liquid drops in contact with a solid surface is strongly affected by contact angle hysteresis and interfacial pinning. However, the majority of models proposed for drops sliding over chemical surface patterns consistently neglect the difference between advancing and receding contact angles. In this article, we present a joint experimental and numerical study of the interaction of gravity-driven drops with a chemical step formed at the junction between a hydrophilic and a hydrophobic region. It demonstrates the strong impact of a contact angle hysteresis contrast on the motion of drops at a linear chemical step. Surprisingly, the smallest driving force required to drag the drop across the step onto the lower hydrophobic surface is not observed at a right angle of incidence. Our model reveals that the non-monotonous response of this passive drop 'filter' is solely due to the higher advancing contact angle on the lower surface, and creates an instance where drop motion is affected by dissipation at the contact line rather than by surface energy.
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