Ultrafast spectroscopy reveals coherent oscillations of a phonon-coupled BEC of excitons in an excitonic insulator.

Nanocomposites with tailored optical properties can provide a new degree of freedom for optical design. However, despite their potential these materials remain unused in bulk optical applications. Here we investigate the conditions under which they can be used for such applications using Mie theory, effective medium theories, and numerical simulations based on the finite element method. We show that due to scattering different effective medium regimes have to be distinguished, and that bulk materials can only be realized in a specific parameter range. Our analysis also enables us to quantify the range of validity of different effective medium theories, and identify design rules on how the material's free material parameters should be adjusted for specific applications.

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The excitonic insulator is an intriguing correlated electron phase formed of condensed excitons. A promising candidate is the small band gap semiconductor TaNiSe. Here we investigate the quasiparticle and coherent phonon dynamics in TaNiSe in a time resolved pump probe experiment. Using the models originally developed by Kabanov et al for superconductors (Kabanov et al 1999 Phys. Rev. B 59 1497), we show that the material's intrinsic gap can be described as almost temperature independent for temperatures up to about 250 K to 275 K. This behavior supports the existence of the excitonic insulator state in TaNiSe. The onset of an additional temperature dependent component to the gap above these temperatures suggests that the material is located in the BEC-BCS crossover regime. Furthermore, we show that this state is very stable against strong photoexcitation, which reveals that the free charge carriers are unable to effectively screen the attractive Coulomb interaction between electrons and holes, likely due to the quasi 1D structure of TaNiSe.

Using a 3.1-μm optical parametric chirped-pulse amplifier (OPCPA), we generate a supercontinuum in a step-index chalcogenide fiber that spans from 1.6 to 5.9 μm at the -20  dB points. The rugged step-index geometry allows for long-term operation, while the spectral bandwidth is limited by the transmission of the As2S3 fiber.

Optical polymers cover only a rather narrow range of optical properties. This is a limiting factor for the design of polymer-based optical systems such as smartphone cameras. Moreover, it also poses a problem for femtosecond two-photon lithography, which is a state-of-the-art technology to 3D print high-quality optics from photopolymers. To overcome the limitations of conventional polymers, we introduce nano-inks based on the commonly used photopolymers IP-DIP and IP-S as polymer matrix and zirconium dioxide (ZrO2) nanoparticles. We show that the refractive index and dispersion of these nano-inks can be purposefully tailored by varying the constituent materials and the volume fraction of the nanoparticles. Furthermore, we demonstrate the suitability of our nano-inks for optical applications by 3D printing single micro-lenses and a multi-material achromatic Fraunhofer doublet. Our findings confirm that nanocomposites expand the range of optical properties that are accessible for polymer-based systems and allow for the design of tailored optical materials.

The use of flat diffractive optical elements (DOEs) for broadband applications, e.g. conventional optical systems, requires DOEs that maintain high efficiencies across the required range of wavelengths, angles of incidence, and grating periods. Here we introduce a general framework for how dispersion engineering can be used to design DOEs that fulfill these requirements and use our approach to determine design rules for broadband DOEs. Our analysis shows that the key to making échelette-type gratings (EGs) suitable for broadband optical systems is the development of new optical materials with specific uncommon dispersion properties. Subsequently, we use our framework to design a representative range of prototype EGs, which allows us to link the specifications of an optical system to the requirements on the EGs’ materials. Finally, we show that our design rules apply to all DOEs based on propagation delays including GRIN DOEs and metagratings. Our design rules therefore guide the way towards unlocking the full potential of DOEs for different kinds of broadband applications.

Materials that contain distinct scatterers, for example, nanoparticles, with sizes exceeding 100 nm scatter light heavily and are heterogeneous. In contrast, the atomic or molecular scatterers in conventional optical materials form a homogeneous distribution on the scale of the wavelength. In this paper, the transition between homogeneous and heterogeneous materials is investigated. To this end, a procedure is introduced that allows for retrieving reliable refractive index values from full wave optical numerical simulations of the underlying multibody scattering problem. Using this procedure, it is shown that the concept of an effective refractive index breaks down on multiple levels as a material transitions out of the homogeneous regime. These findings allow for quantifying how novel dispersion‐engineered nanocomposites for bulk optical applications must be designed and show that Maxwell–Garnett‐type effective medium theories are accurate tools for the design of nanocomposites. The procedure can be readily generalized to other types of scatterers, including atoms and molecules and hence guide the design of different kinds of novel materials.