Library of Congress Cataloging-in-PublicationAll rights reserved. This book, or parts thereof, may not be reproduced in any form or by any means, electronic or mechanical, including photocopying, recording or any information storage and retrieval system now known or to be invented, without written permission from the Publisher.For photocopying of material in this volume, please pay a copying fee through the Copyright Clearance Center, Inc., 222 Rosewood Drive, Danvers, MA 01923, USA. In this case permission to photocopy is not required from the publisher. PrefaceIt is hard to find a field in theoretical physics which can compete with the theory of phase transitions and critical phenomena with respect to the number of written textbooks, reviews and monographs. In our opinion, writing a new book can be justified only by treating in a different manner new trends existing in the area. What do we have in mind in our case? There are just a few books on critical phenomena in systems with confined geometry: a collection of reprints [Cardy, ed. (1988)], a collection of reviews [Privman, ed. (1990)], and the monograph [Krech (1994)] on the Casimir effect. Indeed, in some modern texbooks on critical phenomena one can find special chapters devoted to this topic, see, e.g., [Cardy (1996)], [Domb (1996)], [Zinn-Justin (1996)], [Henkel (1999)]. Against the background of the numerous papers that appear annually, the gap in the monographic literature on the subject is obvious. The present book attempts to partially fill up this gap. We hope also to give our modest contribution in spreading the scaling ideas for fruitful interpretation and analysis of phase transitions in classical and quantum systems of finite volume. It is a well known fact that the volume is an irrelevant parameter for the local properties of a macroscopic system and, therefore, can be chosen arbi trary large. The conventional statistical mechanical theory studies abstract systems, consisting of infinitely many particles in an infinite volume, due to the essential simplifications that occur in their description. Moreover, it becomes possible to describe phase transitions mathematically in terms of discontinuous or singular behavior of some thermodynamic functions. In constructing the above, so called thermodynamic limit [Van Hove (1949) VU1Preface tities. For example, in the canonical Gibbs ensemble the increase in the number of particles N has to be accompanied by a proportional increase in the volume V, so that the density p = N/V be constant. Any intensive quantity ay of a finite system can be written in the form ay = a,oo + Say, where a^ is the bulk value and Say is a finite-size correction which tends to zero as V -► oo. The finite-size correction Say contains a more detailed information about the shape of the system and the boundary conditions. Usually, the correction term becomes essential under rather special condi tions, e.g., in the vicinity of a second-order phase transition. When the relevant thermodynamic parameters approach a critical point, t...
The three-dimensional mean spherical model on a hypercubic lattice with a film geometry Lϫϱ 2 under periodic boundary conditions is considered in the presence of an external magnetic field H. The universal Casimir amplitude ⌬ and the Binder's cumulant ratio B are calculated exactly and found to be ⌬ϭ Ϫ2(3)/(5)ϷϪ0.153051 and Bϭ2/͕ͱ5ln 3 ͓(1ϩͱ5)/2͔͖. A discussion on the relations between the finite temperature C function, usually defined for quantum systems, and the excess free energy ͑due to the finite-size contributions to the free energy of the system͒ scaling function is presented. It is demonstrated that the C function of the model equals 4/5 at the bulk critical temperature T c . It is analytically shown that the excess free energy is a monotonically increasing function of the temperature T and of the magnetic field ͉H͉ in the vicinity of T c . This property is supposed to hold for any classical d-dimensional O(n),nϾ2, model with a film geometry under periodic boundary conditions when dр3. An analytical evidence is also presented to confirm that the Casimir force in the system is negative both below and in the vicinity of the bulk critical temperature T c . ͓S1063-651X͑98͒04508-5͔
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