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Kinetic models for bioethanol production from waste sorghum leaves by Saccharomyces cerevisiae BY4743 are presented. Fermentation processes were carried out at varied initial glucose concentrations (12.5-30.0 g/L). Experimental data on cell growth and substrate utilisation fit the Monod kinetic model with a coefficient of determination (R 2 ) of 0.95. A maximum specific growth rate (µ max ) and Monod constant (K S ) of 0.176 h −1 and 10.11 g/L, respectively, were obtained. The bioethanol production data fit the modified Gompertz model with an R 2 value of 0.98. A maximum bioethanol production rate (r p,m ) of 0.52 g/L/h, maximum potential bioethanol concentration (P m ) of 17.15 g/L, and a bioethanol production lag time (t L ) of 6.31 h were observed. The obtained Monod and modified Gompertz coefficients indicated that waste sorghum leaves can serve as an efficient substrate for bioethanol production. These models with high accuracy are suitable for the scale-up development of bioethanol production from lignocellulosic feedstocks such as sorghum leaves.