The occurrence of the second peak (SP) on the dc magnetization curves of iron pnictide and chalcogenide single crystals (the 'fishtail' effect) has been interpreted in surprisingly different ways, involving, for example, a thermally induced square-to-rhombic vortex lattice transition, a crossover between single vortex pinning in the low magnetic field range and pinning of interacting vortices at higher fields, or has been treated similarly to the peak effect close to the upper critical magnetic field. Here we show that the SP in FeSe 1−x Te x single crystals is related to the well documented order-disorder transition in the vortex system, and its evolution in the low-temperature T domain is described by a dynamic energy balance relation. The main argument supporting this approach is the observed strong increase of the field for the onset of the SP with decreasing T down to 2 K, with an inflection-like point located between 3 and 4 K, in agreement with the two-band superconductivity reported for FeSe 1−x Te x .

A Surface Acoustic Wave (SAW) hydrogen sensor with a Pd/ZnO bilayer structure for room temperature sensing operation has been obtained by Pulsed Laser Deposition (PLD). The sensor structure combines a Pd layer with optimized porosity for maximizing mass effects, with the large acoustoelectric effect at the Pd/ZnO interface. The large acoustoelectric effect is due to the fact that ZnO has a surface conductivity which is highly sensitive to chemisorbed gases. The sensitivity of the sensor was determined for hydrogen concentrations between 0.2% and 2%. The limit of detection (LOD) of the bilayer sensor was about 4.5 times better than the single ZnO films and almost twice better than single Pd films.

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The effect of nanostructure of PLD (Pulsed Laser Deposition)-deposited Pd/WO3 sensing films on room temperature (RT) hydrogen sensing properties of SAW (Surface Acoustic Wave) sensors was studied. WO3 thin films with different morphologies and crystalline structures were obtained for different substrate temperatures and oxygen deposition pressures. Nanoporous films are obtained at high deposition pressures regardless of the substrate temperature. At lower pressures, high temperatures lead to WO3 c-axis nanocolumnar growth, which promotes the diffusion of hydrogen but only once H2 has been dissociated in the nanoporous Pd layer. XRD (X-ray Diffraction) analysis indicates texturing of the WO3 layer not only in the case of columnar growth but for other deposition conditions as well. However, it is only the predominantly c-axis growth that influences film sensing properties. Bilayers consisting of nanoporous Pd layers deposited on top of such WO3 layers lead to good sensing results at RT. RT sensitivities of 0.12–0.13 Hz/ppm to hydrogen are attained for nanoporous bilayer Pd/WO3 films and of 0.1 Hz/ppm for bilayer films with a nanocolumnar WO3 structure. SAW sensors based on such layers compare favorably with WO3-based hydrogen detectors, which use other sensing methods, and with SAW sensors with dense Pd/WO3 bilayers.