[1] We determined the descriptive statistical and spatial geostatistical properties of the perchloroethene ln K d and the ln k of a 1.5 m thick by 10 m horizontal transect of the Borden aquifer near the location of the Stanford-Waterloo (SW) tracer experiment. The ln K d distribution is not normal and is right skewed because of a few high values that occur localized in two regions of the transect. In contrast, the ln k data can be characterized by a normal distribution. A linear regression of ln K d on ln k yields a statistically significant positive correlation, also shown at small lags in the cross correlogram. No significant vertical or horizontal trend in the ln K d data was detected. The semivariogram ranges of ln k and ln K d differ from one another in the vertical direction (0.33 ± 0.06 m and 0.20 ± 0.04 m, respectively) and are much less than the horizontal ranges (a few meters). Despite significant effort the horizontal range of ln K d remains poorly characterized because of limitations of the sample locations. Many of the characteristics described above do not match those assumed in prior theoretical studies that examined the importance of various aquifer characteristics on SW tracer transport. We suggest that there is knowledge to be gained by revisiting the conclusions of these prior studies in light of the new information presented here.

We determined that the spatial heterogeneity in aquifer properties governing the reactive transport of volatile organic contaminants is defined by the arrangement of lithofacies. We measured permeability (k) and perchloroethene sorption distribution coefficient (K d ) for lithofacies that we delineated for samples from the Canadian Forces Base Borden Aquifer. We compiled existing data and collected 57 new cores to characterize a 30 m section of the aquifer near the test location of Mackay et al. (1986). The k and K d were measured for samples taken at six elevations from all cores to create a data set consisting of nearly 400 colocated measurements. Through analysis of variance (corrected for multiple comparisons), we determined that the 12 originally mapped lithofacies could be grouped into five relatively distinct chemohydrofacies that capture the variability of both transport properties. The mean of ln k by lithofacies was related to the grain size and the variance was relatively consistent. In contrast, both the mean and variance of ln K d were greater for more poorly sorted lithofacies, which were also typically more coarse-grained. Half of the aquifer sorption capacity occurred in the three highest-sorbing lithofacies but comprised only 20% of its volume. The model of the aquifer that emerged is that of discontinuous scour-fill deposits of medium sand, generally characterized by greater K d and k, within laterally extensive fine-grained to very fine-grained sands of lower K d and k. Our findings demonstrate the importance of considering source rock composition, transport, and deposition processes when constructing conceptual models of chemohydrofacies.

Buried valleys are characteristic features of glaciated landscapes, and their deposits host important aquifers worldwide. Understanding the stratigraphic architecture of these deposits is essential for protecting groundwater and interpreting sedimentary processes in subglacial and ice-marginal environments. The relationships between depositional architecture, topography and hydrostratigraphy in dissected, pre-Illinoian till sheets is poorly understood. Boreholes alone are inadequate to characterize the complex geology of buried valleys, but airborne electromagnetic surveys have proven useful for this purpose. A key question is whether the sedimentary architecture of buried valleys can be interpreted from airborne electromagnetic profiles. This study employs airborne electromagnetic resistivity profiles to interpret the threedimensional sedimentary architecture of cross-cutting buried valleys in a ca 400 km 2 area along the western margin of Laurentide glaciation in North America. A progenitor bedrock valley is succeeded by at least five generations of tunnel valleys that become progressively younger northward. Tunnel-valley infills are highly variable, reflecting under-filled and over-filled conditions. Under-filled tunnel valleys are expressed on the modern landscape and contain fine sediments that act as hydraulic barriers. Over-filled tunnel valleys are not recognized in the modern landscape, but where they are present they form hydraulic windows between deep aquifer units and the land surface. The interpretation of tunnel-valley genesis herein provides evidence of the relationships between depositional processes and glacial landforms in a dissected, pre-Illinoian till sheet, and contributes to the understanding of the complex physical hydrology of glacial aquifers in general.

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