General rightsIt is not permitted to download or to forward/distribute the text or part of it without the consent of the author(s) and/or copyright holder(s), other than for strictly personal, individual use, unless the work is under an open content license (like Creative Commons). Disclaimer/Complaints regulationsIf you believe that digital publication of certain material infringes any of your rights or (privacy) interests, please let the Library know, stating your reasons. In case of a legitimate complaint, the Library will make the material inaccessible and/or remove it from the website. Please Ask the Library: http://uba.uva.nl/en/contact, or a letter to: Library of the University of Amsterdam, Secretariat, Singel 425, 1012 WP Amsterdam, The Netherlands. You will be contacted as soon as possible. ABSTRACT: Two 14 C accelerator mass spectrometry (AMS) wiggle-match dated peat sequences from Denmark and northern England record changes in mire surface wetness reconstructed using plant macrofossil and testate amoebae analyses. A number of significant mid-late Holocene climatic deteriorations (wet shifts) associated with declines in solar activity were recorded (at ca. 2150 cal. yr BC, 740 cal. yr BC, cal. yr AD 930, cal. yr AD 1020, cal. yr AD 1280-1300, cal. yr AD 1640 and cal. yr AD 1790-1830). The wet shifts identified from ca. cal. yr AD 930 are concurrent with or lag decreases in solar activity by 10-50 years. These changes are replicated by previous records from these and other sites in the region and the new records provide improved precision for the ages of these changes. The rapidly accumulating (up to 2-3 yr cm À1, $1310 yr old, 34 14 C dates) Danish profile offers an unprecedented high-resolution record of climate change from a peat bog, and has effectively recorded a number of significant but short-lived climate change events since ca. cal. yr AD 690. The longer time intervals between samples and the greater length of time resolved by each sample in the British site due to slower peat accumulation rates (up to 11 yr cm À1 , $5250 yr old, 42 14 C dates) acted as a natural smoothing filter preventing the clear registration of some of the rapid climate change events. Not all the significant rises in water table registered in the peat bog archives of the British and Danish sites have been caused by solar forcing, and may be the result of other processes such as changes in other external forcing factors, the internal variability of the climate system or raised bog ecosystem.

A method was developed for the analysis of the UV-absorbing sporopollenin monomers p-coumaric acid and ferulic acid in very low numbers of pollen. This enables the analysis of pollen or spores from cultured plants, from herbarium collections, and from sediment, soil, and peat cores. The method involves thermally assisted hydrolysis and methylation using tetramethylammonium hydroxide combined with gas chromatography and mass spectrometry. Pyrolysis, gas chromatographic, and mass spectrometric conditions were optimized for the analysis of minimal amounts of pollen. The method has a detection limit of approximately 60 fresh pollen of Alnus glutinosa and a relative standard deviation of approximately 10% between 100 and 600 pollen.

Peat humification analysis is a widely used palaeoclimate proxy. However, recent studies combining humification with other proxies of mire surface wetness have identified inconsistencies between the records. We illustrate this inconsistency by comparing humification records with plant macrofossil profiles in three ombrotrophic bogs. Peat humification is a measure for organic decay and reflects changing palaeohydrological conditions and former vegetation composition. The resulting signal is considered to be a derived response to climate. However, even minor changes in the botanical composition of the peat may have a significant influence on humification measurements. The implications of this for palaeoclimate studies are discussed. The assumption that climate has been the major influence on variations in humification rests on the botanical composition being relatively homogeneous throughout the peat profile, and is therefore questionable. Consideration should be given to developing species-specific measures of humification and to testing the assumption that the major influence on peat humification is the surface wetness of the bog (and therefore climate).

The full-text may be used and/or reproduced, and given to third parties in any format or medium, without prior permission or charge, for personal research or study, educational, or not-for-prot purposes provided that:• a full bibliographic reference is made to the original source • a link is made to the metadata record in DRO • the full-text is not changed in any way The full-text must not be sold in any format or medium without the formal permission of the copyright holders.Please consult the full DRO policy for further details. AbstractThe disappearance of the previously abundant moss species Sphagnum imbricatum has been investigated at Butterburn Flow, northern England, using organic geochemical, elemental, macrofossil, pollen and testate amoebae analyses.Variations in the assemblage of peat-forming plants were tracked using the macrofossil distributions as well as the relative chain lengths of n-alkanes and concentrations of 5-n-alkylresorcinols and triterpenols. No significant changes to the vegetation assemblage could be detected prior to the loss of S. imbricatum.Variations in water depth were reconstructed using a testate amoebae transfer function and inferred qualitatively using bulk elemental composition and biomarkers for changing redox conditions in the bog sub-surface: the degree of isomerisation in the C 31 hopanes, and the concentrations of bishomohopanol and archaeol. Pollen analysis reconstructed the landscape surrounding the mire and identified indicators for human disturbance. The results suggest that bog surface wetness increased with the transition from Sphagnum imbricatum to Sphagnum magellanicum, but the increase was not large and S. imbricatum had previously survived similar periods of wetness. However, the loss of S. imbricatum coincides with increasing human disturbance surrounding the bog, which may have altered nutrient inputs to the bog surface from agriculturally derived dust, to the detriment of S. imbricatum but to the benefit of S. magellanicum and Eriophorum vaginatum. It is proposed here that the stresses imposed by the combination of changing nutrient inputs and a rapidly rising water table drove the disappearance of S. imbricatum from Butterburn Flow at ca. cal.AD 1300.