SiNN-pincer iridium complexes were synthesised and demonstrated to catalyse deuteration of trialkylsilanes with benzene-d6 through H/D exchange at room temperature.
Unsaturated 16-electron iridium and rhodium complexes bearing a silyl–bipyridine-based SiNN-pincer ligand (BpySiNN) were synthesised and characterised by X-ray crystallography and NMR spectroscopy. The iridium–BpySiNN complex facilitated the catalytic C(sp2)–H borylation...
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