Various tumor types exhibit the spectral fingerprints in the absorption and reflection spectra in visible and especially in near- to short-wave-infrared wavelength ranges. For the purpose of spectral tumor diagnostics by means of diffuse reflectance spectroscopy, we developed a broadband light emitting diode (LED) source consisting of a blue LED for optical excitation, Lu3Al5O12:Ce3+,Cr3+ luminescent garnet for visible to near infrared emissions, and Bismuth doped GeO2 luminescent glass for near-infrared to short-wave infrared emissions. It emits broad-band light emissions continuously in 470–1600 nm with a spectral gap at 900–1000 nm. In comparison to the currently available broadband light sources like halogen lamps, high-pressure discharge lamps and super continuum lasers, the light sources of this paper has significant advantages for spectral tissue diagnostics in high-spectral stability, improved light coupling to optical fibers, potential in low light source cost and enabling battery-drive.
The phenol degradation processes by pulsed corona discharges are
investigated under three kinds of discharge atmosphere (air, argon and
oxygen). The temporal variations of the concentrations of phenol and the
intermediate products are monitored by LIF spectroscopy. The species of
the intermediate products are identified by spectral analysis. It is
clarified that the oxidative gaseous reagents produced from O2 and
those from H2O degrade phenol to intermediate products with comparable
degradation rates. The degradation via the reagents from H2O gives rise
to the formation of molecules exhibiting fluorescence at 400-500 nm, in
addition to dihydroxybenzene (DHB), while the degradation via the reagents
from O2 produces only DHB. The reagents from O2 play an important
role in the conversion of phenol to DHB.
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