The Coulomb interaction among massless chiral particles harbors unusual emergent phenomena in solids beyond the conventional realm of correlated electron physics. An example of such an effect is excitonic condensation of interacting massless Dirac fermions, which drives spontaneous mass acquisition and whose exact nature remains actively debated. Its precursor fluctuations growing prior to the condensate have been suggested by a recent nuclear magnetic resonance study in an organic material, hosting a pair of two-dimensional (2D) tilted Dirac cones at charge neutrality. Here, we theoretically study the excitonic transition in 2D tilted cones to understand the electron-hole pairing instability as functions of temperature (T), chemical potential (μ), and in-plane magnetic field (H). By solving a gap equation within a weak-coupling treatment and incorporating self-energy effects due to the Coulomb interaction through a renormalization-group technique, we calculate excitonic instability in a T-μ-H parameter space, and find that the pairing is promoted as H is increased but suppressed as μ moves away from the charge-neutrality point. We show that these findings are explained by enhanced or degraded Fermi-surface nesting between the Zeeman-induced pockets connecting the two tilted cones. Furthermore, to evaluate the precursor excitonic fluctuations in relation to this diagram, we consider the Coulomb interaction via a ladder-type approximation and calculate the nuclear spin-lattice relaxation rate, which provides rational ways to understand otherwise puzzling experimental results in the organic material by the μ and H dependence of the instability.
Motivated by the recent discovery of Dirac nodal line in the single-component molecular conductor [Pt(dmdt) 2 ], we propose a three-orbital tight-binding model based on the Wannier fitting of the first-principles calculation, and address the problems of edge states, topological properties and magnetic susceptibility. We find that logarithmic peaks of the local density of states emerge near the Fermi energy, owing to pseudo-one-dimensional edge states that appear between the Dirac nodal lines. Magnetic susceptibility calculated in our model can explain the experimental result at a high temperature. In the presence of a realistic spin-orbit coupling, we show that [Pt(dmdt) 2 ] is a topological nodal line semimetal with isolated electron and hole pockets.
The optical conductivity in the charge order phase is calculated in the two-dimensional extended Hubbard model describing an organic Dirac electron system α-(BEDT-TTF) 2 I 3 using the mean field theory and the Nakano-Kubo formula. Because the interband excitation is characteristic in a two-dimensional Dirac electron system, a peak structure is found above the charge order gap. It is shown that the peak structure originates from the Van Hove singularities of the conduction and valence bands, where those singularities are located at a saddle point between two Dirac cones in momentum space. The frequency of the peak structure exhibits drastic change in the vicinity of the charge order transition.
Motivated by the results of recent transport and optical conductivity studies, we propose a semiinfinite two-dimensional lattice model for interacting massive Dirac electrons in the pressurized organic conductor α-(BEDT-TTF)2I3, and address the problem of domain wall conductivity in a charge-ordered insulating phase under realistic experimental conditions. Using the extended Hubbard model at a mean field level, we present results of extensive numerical studies around the critical region of the model, reporting on the resistivity and optical conductivity calculated by means of the Nakano-Kubo formula. We find that the activation gap extracted from the resistivity data can be much smaller than the optical gap in the critical region, which is induced by metallic conduction along an one-dimensional domain wall emerging at the border of two charge-ordered ferroelectric regions with opposite polarizations. The data are consistent with the observed transport gap in real α-(BEDT-TTF)2I3 samples that is reduced remarkably faster than the optical gap upon suppressing charge order with pressure. Our optical conductivity also reveals an additional shoulder-like structure at low energy inside the gap, which is argued to be directly relevant to the metallic bound states residing on the domain wall. arXiv:1904.03884v2 [cond-mat.mes-hall]
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