Removal of heavy metal ions from wastewater is of prime importance for a clean environment and human health. Different reported methods were devoted to heavy metal ions removal from various wastewater sources. These methods could be classified into adsorption-, membrane-, chemical-, electric-, and photocatalytic-based treatments. This paper comprehensively and critically reviews and discusses these methods in terms of used agents/adsorbents, removal efficiency, operating conditions, and the pros and cons of each method. Besides, the key findings of the previous studies reported in the literature are summarized. Generally, it is noticed that most of the recent studies have focused on adsorption techniques. The major obstacles of the adsorption methods are the ability to remove different ion types concurrently, high retention time, and cycling stability of adsorbents. Even though the chemical and membrane methods are practical, the large-volume sludge formation and post-treatment requirements are vital issues that need to be solved for chemical techniques. Fouling and scaling inhibition could lead to further improvement in membrane separation. However, pre-treatment and periodic cleaning of membranes incur additional costs. Electrical-based methods were also reported to be efficient; however, industrial-scale separation is needed in addition to tackling the issue of large-volume sludge formation. Electric- and photocatalytic-based methods are still less mature. More attention should be drawn to using real wastewaters rather than synthetic ones when investigating heavy metals removal. Future research studies should focus on eco-friendly, cost-effective, and sustainable materials and methods.

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Abstract-Membrane distillation (MD) is a potential mean of water desalination. MD is a thermally driven desalination technology that has been employed in four basic configurations. One of these configuration is Direct Contact Membrane Distillation (DCMD). In DCMD, both hot and cold solution is maintained in direct contact with micro porous hydrophobic membrane material. Heat and mass transfer analysis was performed on DCMD. Based on Kinetic theory of gas, the performance of different models of membrane permeability (coefficient) was investigated under different DCMD operating parameters (feed temperature, coolant temperature and feed flow rate). Knudsen number provides the guideline in identifying the type of model of mass transfer to be considered under any given experimental conditions.Results revealed that for a given pore size under the same simulation and experimental conditions, Transition (KnudsenMolecular diffusion) type of flow model predictions is in good agreement with the experimental results. Hence the best model to be consider for flux prediction in DCMD. The effect of membrane pore size was also studied. Results showed that permeate flux increases with increase in pore size up to the critical pore condition where the flux prediction remain constant (unchanged).Index Terms-Desalination, direct contact membrane distillation, flux prediction, hydrophobic membrane material.