A new strategy for noninvasive temperature probing, applying the temperature-induced configuration crossover between the thermally-coupled 6P7/2 and 5d1 levels of Eu2+ is presented.
A blue-green
luminescence of SrS:Ce has been known for years. High-density sintered
pellets of SrS:Ce were prepared for the first time and their unique
spectroscopic properties are reported. A new luminescence band appearing
in red and infrared part of spectrum and having all the characteristics
of Ce3+ emission was obtained after sintering SrS:Ce at
1700 °C. The excitation features of the regular (blue-green)
and the new, anomalous emissions are very much different. Together,
both excitations spectra cover the whole range of UV and blue part
of spectrum. Such characteristics allow for site-selective excitation
of both centers. Experiments in the 25–435 K range of temperatures
show that the new, anomalous Ce3+ emitting center hardly
interacts with the regular one. Only excitation around 425 nm leads
to superimposed emissions of both centers, especially at higher temperatures.
Decay traces show that the regular center decay time is pretty constant
between 25 and 435 K (shortens from 25 to 23 ns). However, the anomalous
center shows monoexponential decay only at 25 K with time constant
of 79 ns, and at room temperature its trace is two-exponential with
components of 5 ns (20%) and 50 ns (80%). Aggregation of the dopant
ions and its excessive charge compensating defects were postulated
to lead to the [Ce3+–S2––Ce3+] or [Ce3+–VSr
″–Ce3+] clusters.
The spectroscopic data on the anomalous luminescence were also shown
to adhere with the possibility of Ce3+/Ce4+ intervalence
charge transfer luminescence and semiquantitative scheme for relevant
processes was presented.
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