Wood plastic composites (WPC) are mainly used as an outdoor material, so durability against fungal decay is one of the factors that should be analyzed and if necessary improved. WPC are susceptible to biodegradation, although these materials have limited water absorption because of the wood fiber encapsulation in polymer matrix. In the study two different water pretreatment methods (short-term and long-term) were used to ensure appropriate water content for fungal growth. Also in the paper thermally modified wood (different regimes) fiber influence on WPC fungal resistance is investigated. The results showed that long-term water pretreated WPC specimens had more suitable conditions for fungal degradation that led to higher weight loss. The results which were related to thermally modified wood fibers showed, that WPC with thermally modified wood fibers had improved resistance against fungi. Thermal modification regimes had an effect on WPC durability as well.
Thermally modified (TM) wood production has significantly increased in the last decade. The trend for TM wood residues should be similarrapidly increasing, which has prompted this research on the possible efficient uses of these residues, such as sawdust. One of the possibilities could be the production of wood plastic composites (WPCs). In this work, three different hydrothermal modification regimes were used to modify birch boards. Modified and unmodified birch boards were milled to obtain sawdust. WPCs were made with a two-roll mill, and they consisted of 50 wt-% wood fibres + 50 wt-% polypropylene. Melt flow index (MFI), flexural properties, impact strength, microhardness water absorption and dimensional stability were tested. WPCs with TM wood showed improvement in flexural properties, MFI and other properties, however there was a decrease in impact strength. Scanning electron microscopy pictures of impact strength samples fracture surfaces were taken.
The chemical structure of wood changes significantly during thermal modification, significantly influencing the behaviour of wood during weathering. In this study, the effect of different wavelength ranges on thermally modified and unmodified aspen (Populus tremula L.) wood during solar irradiation was investigated. Irradiation was performed by exposing wood to natural solar irradiation under filters transmitting different wavelength ranges. For both woods, the magnitude of characteristic change (discolouration, changes in reflectance, and chemical composition) clearly depended on the solar wavelength bands, but the trends of the changes differed. For unmodified wood, the magnitude of the characteristic changes increased as the portion of shortwavelength radiation in the light increased. However, UV radiation was not found to be the dominant factor influencing changes in thermally modified wood during solar irradiation. The colour and chemical structure of thermally modified wood changed substantially for all studied irradiation conditions.
Thermal modification of wood has gained its niche in the production of materials that are mainly used for outdoor applications, where the stability of aesthetic appearances is very important. In the present research, spectral sensitivity to discoloration of thermally modified (TM) aspen wood was assessed and, based on these results, the possibility to delay discoloration due to weathering by non-film forming coating containing transparent iron oxides in the formulation was studied. The effect of including organic light stabilizers (UVA and HALS) in coatings as well as pretreatment with lignin stabilizer (HALS) was evaluated. Artificial and outdoor weathering was used for testing the efficiency of different coating formulations on TM wood discoloration. For color measurements and discoloration assessment, the CIELAB color model was used. Significant differences between the spectral sensitivity of unmodified and TM wood was observed by implying that different strategies could be effective for their photostabilization. From the studied concepts, the inclusion of the transparent red iron oxide into the base formulation of the non-film forming coating was found to be the most effective approach for enhancing TM wood photostability against discoloration due to weathering.
The processing of wood produces large amounts and different types of wood residues. Currently, a part of these residues is used in the production of wood plastic composites (WPC). It is known that wood particle characteristics (size, length/diameter ratio, shape, etc.) significantly influence properties of WPC; however, for thermally modified wood, the information about these effects is limited. Therefore, the main objective of this research was to investigate how different size fractions of thermally modified wood particles influence mechanical and water resistance properties of WPC. The results showed that the particle size had a significantly smaller influence on the mechanical properties for WPC with thermally modified wood particles compared to WPC with unmodified wood particles. Additionally, the wood particle size had no effect on water absorption dynamics and ultimate water uptake in case of thermally modified wood particles. Finally, wood particle size did not affect changes in mechanical properties for re-dried WPC after 200 days of immersion in water.
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