Results related to the energy transfer in the rare gas mixtures are reported for an electrical discharge excitation with plasma expansion and a heavy-ion-beam excitation. Energy transfer from the lighter rare gases to the heavier ones was observed in a very efficient way for both excitation mechanisms. Strong emission from excited atomic states, which are possible candidates for new lasers, was observed for the electrical discharge case. The broad-band emission of the discharge sources makes them appropriate for strong lamps in the VUV. Some comparisons of the two excitation mechanisms were discussed with respect to the energy deposition, the density of dimers and their vibrational relaxation.