The paper presents the results of systematic measurements of the thermal conductivity coefficient of nanofluids at room temperature. In total, more than fifty various nanofluids based on water, ethylene glycol, and engine oil containing particles of SiO2, Al2O3, TiO2, ZrO2, CuO, and diamond were studied. The nanoparticles volume concentration ranged from 0.25 to 8% and the particles size ranged from 10 to 150 nm. It is shown that the thermal conductivity of nanofluids is not described by the classical theories (Maxwell's and so forth). The nanofluid thermal conductivity coefficient is a complicated function not only of the particle concentration, but also the particles size, their material, and type of base fluid. Measured thermal conductivity coefficients almost always exceed the values calculated by the Maxwell's formula, though nanofluids with sufficiently small particles may have thermal conductivity coefficients even lower than those predicted by the Maxwell theory. However, in all cases, the nanofluid thermal conductivity coefficient enhances with increasing particle size. It is convincingly shown that there is no direct correlation between the thermal conductivity of the nanoparticle material and the thermal conductivity of nanofluid containing these particles. The base liquid also significantly influences the effective thermal conductivity of the nanofluid. It has been confirmed that the lower the thermal conductivity of the base fluid, the higher the relative thermal conductivity coefficient of the nanofluid.
The unique properties of supercritical fluid technology have found wide application in various industry sectors. Supercritical fluids allow for the obtainment of new types of products with special characteristics, or development and design of technological processes that are cost-effective and friendly to the environment. One of the promising areas where supercritical fluids, especially carbon dioxide, can be used is the oil industry. In this regard, the present review article summarizes the results of theoretical and experimental studies of the use of supercritical fluids in the oil and gas industry for supercritical extraction in the course of oil refining, increasing oil recovery in the production of heavy oil, hydraulic fracturing, as well as processing and disposal of oil sludge and asphaltenes. At the end of the present review, the issue of the impact of supercritical fluid on the corrosion of oil and gas equipment is considered. It is found that supercritical fluid technologies are very promising for the oil industry, but supercritical fluids also have disadvantages, such as expansion or incompatibility with materials (for example, rubber).
The effect of nanoparticles of various chemical components and sizes on the rheological behaviour of drilling fluids, pressure loss and cuttings transport in the vertical borehole for a laminar flow regime is considered in the paper. The results of numerical and experimental studies are presented. Silicon, aluminium and titanium oxides nanoparticles are considered. A drilling fluid is Bentonite-water solution with a mass fraction of 5%. The particles concentration in the solution was varied from 0.25 to 2 weight percentages and the particles sizes ranged from 5 to 50 nm. The dependences of the effective viscosity and rheological parameters of the solutions on the nanoparticles concentrations, sizes and materials were obtained. It was shown that nanoparticles in drilling fluid increase cuttings transport by 17% and decrease the average slip velocity of the sludge particles in 1.7 to 2.0 times, but the pressure losses when pumping the drilling fluid increase in 2.5 times.
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