Of the two-phase mixture models used to study deflagration-to-detonation transition in granular explosives, the Baer–Nunziato model is the most highly developed. It allows for unequal phase velocities and phase pressures, and includes source terms for drag and compaction that strive to erase velocity and pressure disequilibria. Since typical time scales associated with the equilibrating processes are small, source terms are stiff. This stiffness motivates the present work where we derive two reduced models in sequence, one with a single velocity and the other with both a single velocity and a single pressure. These reductions constitute outer solutions in the sense of matched asymptotic expansions, with the corresponding inner layers being just the partly dispersed shocks of the full model. The reduced models are hyperbolic and are mechanically as well as thermodynamically consistent with the parent model. However, they cannot be expressed in conservation form and hence require a regularization in order to fully specify the jump conditions across shock waves. Analysis of the inner layers of the full model provides one such regularization [Kapila et al., Phys. Fluids 9, 3885 (1997)], although other choices are also possible. Dissipation associated with degrees of freedom that have been eliminated is restricted to the thin layers and is accounted for by the jump conditions.

The detonation stability problem is studied by a normal mode approach which greatly simplifies the calculation of linear instability of detonation in contrast to the Laplace transform procedure used by Erpenbeck. The method of solution, for an arbitrary parameter set, is a shooting method which can be automated to generate easily the required information about instability. The condition on the perturbations applied at the end of the reaction zone is shown to be interpreted as either a boundedness condition or an acoustic radiation condition. Continuous and numerically exact neutral stability curves and boundaries are given as well as growth rates and eigenfunctions which are calculated for the first time. Our calculations include the Chapman–Jouguet (CJ) case which presents no special difficulty. We give representative results for our detonation model and summarize the one-dimensional stability behaviour in parameter space. Comparison with previous results for the neutral stability boundaries and approximations to the unstable discrete spectrum are given. Parametric studies of the unstable, discrete spectrum's dependence on the activation energy and the overdrive factor are given with the implications for interpreting the physical mechanism of instability observed in experiments. This first paper is restricted to the case of one-dimensional linear instability. Extensions to transverse disturbances will be treated in a sequel.

The two-phase mixture model developed by Baer and Nunziato ͑BN͒ to study the deflagration-to-detonation transition ͑DDT͒ in granular explosives is critically reviewed. The continuum-mixture theory foundation of the model is examined, with particular attention paid to the manner in which its constitutive functions are formulated. Connections between the mechanical and energetic phenomena occurring at the scales of the grains, and their manifestations on the continuum averaged scale, are explored. The nature and extent of approximations inherent in formulating the constitutive terms, and their domain of applicability, are clarified. Deficiencies and inconsistencies in the derivation are cited, and improvements suggested. It is emphasized that the entropy inequality constrains but does not uniquely determine the phase interaction terms. The resulting flexibility is exploited to suggest improved forms for the phase interactions. These improved forms better treat the energy associated with the dynamic compaction of the bed and the single-phase limits of the model. Companion papers of this study ͓Kapila et al., Phys. Fluids 9, 3885 ͑1997͒; Kapila et al., in preparation; Son et al., in preparation͔ examine simpler, reduced models, in which the fine scales of velocity and pressure disequilibrium between the phases allow the corresponding relaxation zones to be treated as discontinuities that need not be resolved in a numerical computation.

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A detailed investigation of the hydrodynamic stability to transverse linear disturbances of a steady, one-dimensional detonation in an ideal gas undergoing an irreversible, unimolecular reaction with an Arrhenius rate constant is conducted via a normal-mode analysis. The method of solution is an iterative shooting technique which integrates between the detonation shock and the reaction equilibrium point. Variations in the disturbance growth rates and frequencies with transverse wavenumber, together with two-dimensional neutral stability curves and boundaries for all unstable low- and higher frequency modes, are obtained for varying detonation bifurcation parameters. These include the detonation overdrive, chemical heat release and reaction activation energy. Spatial perturbation eigenfunction behaviour and phase and group velocities are also obtained for selected sets of unstable modes. Results are presented for both Chapman–Jouguet and overdriven detonation velocities. Comparisons between the earlier pointwise determination of stability and interpolated neutral stability boundaries obtained by Erpenbeck are made. Possible physical mechanisms which govern the wavenumber selection underlying the initial onset of either regular or irregular cell patterns are also discussed.