ACTIVATION OF ELECTRODE SURFACES 83g an essentially linear growth (i.e., constant growth rate) regardless of the relative importance of the oxide formation in the over-all anodic process \ b / L (t) ~ [ (Lo --L1) --L1 log to] Jr Lit [15']Another interesting point would be the variation of the critical time with pertinent process parameters under galvanostatic conditions in view of the welldocumented difference in the growth rate vs. time rerelationship with respect to potentiostatic conditions [e.g., (7)], in the instance of Pt anodes. Since galvanostatic conditions are less inviting than potentiostatic conditions for a rotating wiper-blade electrode, such an investigation would be beyond the scope of our current research. The hereby presented analysis of critical time would most likely prove useful in improved design of wiper-blade electrode systems both for mechanism studies and practical oxidations at the continuously activated electrode surface, by choosing appropriate rotation rates and wiper-blade widths for a given electrode metal and specific electrochemical reactions.
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