No abstract

Urban pollution can often impact surrounding, non-urban regions, through advection and dispersal of pollutants by the prevailing winds. Urban regions located upstream of high mountains, such as the Andes, can potentially impact the cryosphere by deposition of particles onto the surface of the snowpack and glaciers.Santiago, the capital of Chile, has more than 6 million inhabitants and regularly experiences episodes of severe pollution, particularly during the austral winter. Some studies have hypothesized that particle pollution from Santiago can reach the cryosphere downwind of the city, but the scarcity of measurements made high in the mountains prevents the validation of mesoscale models so the proof of actual impact remains elusive. A research project was designed to provide some insight into this question. The Pollution Impact on Snow in the Cordillera -Experiments and Simulations (PISCES) project was carried out in 2014 and includes both observational and modeling components. A five-week field campaign was conducted at the end of winter, at an elevated site in a mountain valley, 65 km to the southeast of the center of Santiago, to characterize some aspects of particulate pollution.During synoptic conditions that result in clear days at the site, the mesoscale mountain-valley circulation is effective in transporting pollutants upwards during the day, leading to diluted particle concentrations beyond the summits of the highest peaks. Cloudy days with reduced up-valley circulation do not show increased concentrations associated with transport. Back trajectories indicate that air masses reaching the site during the field campaign are seldom influenced by pollution from Santiago.

In this work, we describe a method to estimate the precipitable water vapor (PWV) from Geostationary Observational Environmental Satellite (GOES) data at high altitude sites. The method was applied at Atacama Pathfinder Experiment (APEX) and Cerro Toco sites, located above 5000 m altitude in the Chajnantor plateau, in the north of Chile. It was validated using GOES-12 satellite data over the range 0-1.2 mm since submillimeter/millimeter astronomical observations are only useful within this PWV range. The PWV estimated from GOES and the Final Analyses (FNL) at APEX for 2007 and 2009 show root mean square error values of 0.23 mm and 0.36 mm over the ranges 0-0.4 mm and 0.4-1.2 mm, respectively. However, absolute relative errors of 51% and 33% were shown over these PWV ranges, respectively. We recommend using high-resolution thermodynamic profiles from the Global Forecast System (GFS) model to estimate the PWV from GOES data since they are available every three hours and at an earlier time than the FNL data. The estimated PWV from GOES/GFS agrees better with the observed PWV at both sites during night time. The largest errors are shown during daytime. Short-term PWV forecasts were implemented at both sites, applying a simple persistence method to the PWV estimated from GOES/GFS. The 12 h and 24 h PWV forecasts evaluated from August to October 2009 indicates that 25% of them show a very good agreement with observations whereas 50% of them show reasonably good agreement with observations. Transmission uncertainties calculated for PWV estimations and forecasts over the studied sites are larger over the range 0-0.4 mm than over the range 0.4-1.2 mm. Thus, the method can be used over the latter interval with more confidence.

No abstract

The Radiative Heating in Underexplored Bands Campaign (RHUBC-II) project was held from August to October 2009 in the Atacama Desert in Chile at 5320-m altitude. Observations from this experiment and a high-resolution numerical simulation with the Weather Research and Forecasting Model (WRF) were used to understand the structure and evolution of the atmosphere over a region with complex terrain and extremely dry environmental conditions. The mechanisms driving the local circulations during synoptically unperturbed conditions at the field site were studied. The study suggests that the field site is mainly affected by a mountain-scale and a plateau-scale thermally driven circulation. The latter seems to dominate. The advection of warm air by downslope flows from higher heights during nighttime may be the mechanism that counteracts the longwave radiative cooling at the surface, causing a small decrease of near-surface temperature during the night. WRF represents the near-surface and upper atmosphere reasonably well above the RHUBC-II site. Important orographic features are misrepresented in the model terrain, which may cause the observed differences in near-surface winds. The zonal pressure gradient between both sides of the mountain and the static stability of the air mass on the windward side of the terrain control the local circulations over the field site. Consequently, a misrepresentation of these mechanisms in the model may cause differences between the simulated winds and observations.