Abstract. Slowly accumulated (<5 cm kyr '1) and rapidly accumulated (5-20 cm kyr -1) sediments have been compared to define the initiation and termnation times of the most recent sapropel (S1) in the eastern Mediterranean Sea. The Ba/A1 ratio has been employed as a more persistent index of productivity than C•g. Accelerator mass spectrometry radiocarbon dating of pelagic foraminifera indicates a maximum duration for increased Ba/A1 levels in S 1 from -9500-6000 (uncorrected radiocarbon convention years B.P.) in the rapidly accumulated sediments and -9500-5300 years B.P. in the slowly accumulated sediments. This difference is ascribed to bioturbation affecting the slower accumulated S1 sediments. In the two most rapidly accumulated S1 units, from the Adriatic and Aegean Seas, there is a "saddle" of lower values centered on 7500 years B.P. in the Corg and Ba/AI profiles, so that the visual S 1 unit appears as a doublet. Geochemical evidence indicates that this intervening period is best interpreted as an episode of increased ventilation and bottom water oxygenation during the period of sapropel accumulation.

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Abstract-In the succession of redox conditions encountered with increasing depth in sediments, the first major redox change is the oxic/post-oxic boundary. The geochemical behaviour of Hg is investigated in three different deep-sea situations where this boundary has been localised within a narrow depth zone for a sustained period (thousands of years) because of changes in sedimentary accumulation conditions. From previous work it is known that a variety of redox-sensitive elements form diagenetic peak concentrations above and below this boundary. This work shows for the first time that Hg also develops sharp peaks immediately into post-oxic conditions in two different situations where sediments containing trace pyrite have been re-oxidised. The Hg peaks are always closely associated with corresponding Se peaks, and the diagenetic concentrations of both elements are persistent over millions of years on subsequent burial into more reducing conditions. There is an apparent offset in the locations of Hg and Se peaks observed in a continuously accumulated case where Se uptake from bottom waters occurs independently of pyrite formation or re-oxidation, which may be a consequence of a widely spread Se peak. It is proposed that formation of the HgSe species tiemannite is involved, by analogy with selenium ore occurrences and the other elements found immobilised along with Se and Hg in the cases studied.

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