We present 75As nuclear magnetic resonance data from measurements of a series of Ba(Fe(1-x)Co(x))2As2 crystals with 0.00≤x≤0.075 that reveals the coexistence of frozen antiferromagnetic domains and superconductivity for 0.060≤x≤0.071. Although bulk probes reveal no long range antiferromagnetic order beyond x=0.06, we find that the local spin dynamics reveal no qualitative change across this transition. The characteristic domain sizes vary by more than an order of magnitude, reaching a maximum variation at x=0.06. This inhomogeneous glassy dynamics may be an intrinsic response to the competition between superconductivity and antiferromagnetism in this system.

The heavy electron Kondo liquid is an emergent state of condensed matter that displays universal behavior independent of material details. Properties of the heavy electron liquid are best probed by NMR Knight shift measurements, which provide a direct measure of the behavior of the heavy electron liquid that emerges below the Kondo lattice coherence temperature as the lattice of local moments hybridizes with the background conduction electrons. Because the transfer of spectral weight between the localized and itinerant electronic degrees of freedom is gradual, the Kondo liquid typically coexists with the local moment component until the material orders at low temperatures. The two-fluid formula captures this behavior in a broad range of materials in the paramagnetic state. In order to investigate two-fluid behavior and the onset and physical origin of different long range ordered ground states in heavy electron materials, we have extended Knight shift measurements to URu 2 Si 2 , CeIrIn 5 , and CeRhIn 5 . In CeRhIn 5 we find that the antiferromagnetic order is preceded by a relocalization of the Kondo liquid, providing independent evidence for a local moment origin of antiferromagnetism. In URu 2 Si 2 the hidden order is shown to emerge directly from the Kondo liquid and so is not associated with local moment physics. Our results imply that the nature of the ground state is strongly coupled with the hybridization in the Kondo lattice in agreement with phase diagram proposed by Yang and Pines.nuclear magnetic resonance | heavy fermion | hyperfine couplings C ompetition between different energy scales gives rise to a rich spectrum of emergent ground states in strongly correlated electron materials. In the heavy fermion compounds, a lattice of nearly localized f electrons interacts with a sea of conduction electrons, and depending on the magnitude of this interaction different types of long-range order may develop at low temperatures (1). The Kondo lattice model strives to capture the essential physics of heavy fermion materials by considering the various magnetic interactions between the conduction electron spins, S c , and the local moment spins, S f (2). Different ground states can emerge depending on the relative strengths of the interaction, J, between S c and S f and the intersite interaction, J f f , between the S f spins (3, 4). Much of the physics of the phase diagram is driven by a quantum critical point, which separates long-range ordered ground states from those in which the local moments have fully hybridized with the conduction electrons to form itinerant states with large effective masses and large Fermi surfaces (5). In several materials quantum critical fluctuations give rise to anomalous non-Fermi liquid behavior in various bulk transport and thermodynamic quantities (6-8).In recent years, evidence has emerged that in the high temperature disordered phase the electronic degrees of freedom simultaneously exhibit both itinerant and localized behavior (9). Below a temperature T Ã that marks the onset...

We present magnetotransport and 209 Bi nuclear magnetic resonance (NMR) data on a series of single crystals of Bi2Se3, Bi2Te2Se and CuxBi2Se3 with varying carrier concentrations. The Knight shift of the bulk nuclei is strongly correlated with the carrier concentration via a hyperfine coupling of 27 µeV, which may have important consequences for scattering of the protected surface states. Surprisingly we find that the NMR linewidths and the spin lattice relaxation rate appear to be dominated by the presence of localized spins, which may be related to the presence of Se vacancies.

Resistivity, magnetization and microscopic 75 As nuclear magnetic resonance (NMR) measurements in the antiferromagnetically ordered state of the iron-based superconductor parent material CaFe2As2 exhibit anomalous features that are consistent with the collective freezing of domain walls. Below T * ≈ 10 K, the resistivity exhibits a peak and downturn, the bulk magnetization exhibits a sharp increase, and 75 As NMR measurements reveal the presence of slow fluctuations of the hyperfine field. These features in both the charge and spin response are strongly field dependent, are fully suppressed by H * ≈ 15 T, and suggest the presence of filamentary superconductivity nucleated at the antiphase domain walls in this material.

Charge transport in conjugated polymers may be governed not only by the static microstructure but also fluctuations of backbone segments. Using molecular dynamics simulations, we predict the role of side chains in the backbone dynamics for regiorandom poly(3-alkylthiophene-2,5-diyl)s (P3ATs). We show that the backbone of poly(3-dodecylthiophene-2-5-diyl) (P3DDT) moves faster than that of poly(3-hexylthiophene-2,5-diyl) (P3HT) as a result of the faster motion of the longer side chains. To verify our predictions, we investigated the structures and dynamics of regiorandom P3ATs with neutron scattering and solid state NMR. Measurements of spinlattice relaxations (T 1 ) using NMR support our prediction of faster motion for side chain atoms that are farther away from the backbone. Using small-angle neutron scattering (SANS), we confirmed that regiorandom P3ATs are amorphous at about 300 K, although microphase separation between the side chains and backbones is apparent. Furthermore, quasi-elastic neutron scattering (QENS) reveals that thiophene backbone motion is enhanced as the side chain length increases from hexyl to dodecyl. The faster motion of longer side chains leads to faster backbone dynamics, which in turn may affect charge transport for conjugated polymers.