Context. Barium and S stars without technetium are red giants suspected of being all members of binary systems. Aims. This paper provides both long-term and revised, more accurate orbits for barium and S stars adding to previously published ones. The sample of barium stars with strong anomalies comprise all such stars present in the Lü et al. catalogue. Methods. Orbital elements are derived from radial velocities collected from a long-term radial-velocity monitoring performed with the HERMES spectrograph mounted on the Mercator 1.2 m telescope. These new measurements were combined with older, CORAVEL measurements. With the aim of investigating possible correlations between orbital properties and abundances, we collected as well an as homogeneous as possible set of abundances for barium stars with orbital elements. Results. We find orbital motion for all barium and extrinsic S stars monitored. We obtain the longest period known so far for a spectroscopic binary involving an S star, namely 57 Peg with a period of the order of 100 -500 yr. We present the mass distribution for the barium stars, which ranges from 1 to 3 M , with a tail extending up to 5 M in the case of mild barium stars. This high-mass tail comprises mostly high-metallicity objects ([Fe/H] ≥ −0.1). Mass functions are compatible with WD companions whose masses range from 0.5 to 1 M . Strong barium stars have a tendency to be found in systems with shorter periods than mild barium stars, although this correlation is rather lose, metallicity and WD mass playing a role as well. Using the initial -final mass relationship established for field WDs, we derived the distribution of the mass ratio q = M AGB,ini /M Ba (where M AGB,ini is the WD progenitor initial mass, i.e., the mass of the system former primary component) which is a proxy for the initial mass ratio (the more so, the less mass the barium star has accreted). It appears that the distribution of q is highly non uniform, and significantly different for mild and strong barium stars, the latter being characterized by values mostly in excess of 1.4, whereas mild barium stars occupy the range 1 -1.4. Conclusions. The orbital properties presented in this paper pave the way for a comparison with binary-evolution models.

Barium (Ba) dwarfs and CH subgiants are the less evolved analogues of Ba and CH giants. They are F- to G-type main-sequence stars polluted with heavy elements by their binary companions when the companion was on the asymptotic giant branch (AGB). This companion is now a white dwarf that in most cases cannot be directly detected. We present a large systematic study of 60 objects classified as Ba dwarfs or CH subgiants. Combining radial-velocity measurements from HERMES and SALT high-resolution spectra with radial-velocity data from CORAVEL and CORALIE, we determine the orbital parameters of 27 systems. We also derive their masses by comparing their location in the Hertzsprung–Russell diagram with evolutionary models. We confirm that Ba dwarfs and CH subgiants are not at different evolutionary stages, and that they have similar metallicities, despite their different names. Additionally, Ba giants appear significantly more massive than their main-sequence analogues. This is likely due to observational biases against the detection of hotter main-sequence post-mass-transfer objects. Combining our spectroscopic orbits with the HIPPARCOS astrometric data, we derive the orbital inclination and the mass of the WD companion for four systems. Since this cannot be done for all systems in our sample yet (but should be possible with upcoming Gaia data releases), we also analyse the mass-function distribution of our binaries. We can model this distribution with very narrow mass distributions for the two components and random orbital orientations on the sky. Finally, based on BINSTAR evolutionary models, we suggest that the orbital evolution of low-mass Ba systems can be affected by a second phase of interactions along the red giant branch of the Ba star, which impact the eccentricities and periods of the giants.

Context. Barium stars are s-process enriched giants. They owe their chemical peculiarities to a past mass transfer phase. During this phase they were polluted by their binary companion, which at the time was an asymptotic giant branch (AGB) star, but is now an extinct white dwarf. Barium stars are thus ideal targets for understanding and constraining the s-process in low- and intermediate-mass AGB stars. Aims. We derive the abundances of a large number of heavy elements in order to shed light on the conditions of operation of the neutron source responsible for the production of s-elements in the former companions of the barium stars. Methods. Adopting a recently used methodology, we analyse a sample of eighteen highly enriched barium stars observed with the high-resolution HERMES spectrograph mounted on the Mercator telescope (La Palma). We determine the stellar parameters and abundances using MARCS model atmospheres. In particular, we derive the Nb–Zr ratio which was previously shown to be a sensitive thermometer for the s-process nucleosynthesis. Indeed, in barium stars, 93Zr has fully decayed into mono-isotopic 93Nb, so Nb/Zr is a measure of the temperature-sensitive 93Zr/Zr isotopic ratio. Results. HD 28159, previously classified as K5III and initially selected to serve as a reference cool K star for our abundance analysis, turns out to be enriched in s-process elements, and as such is a new barium star. Four stars are characterised by high nitrogen abundances, and among those three have high [Nb/Zr] and [hs/ls] ratios. The derived Zr and Nb abundances provide more accurate constraints on the s-process neutron source, identified to be 13C(α, n)16O for barium stars. The comparison with stellar evolution and nucleosynthesis models shows that the investigated barium stars were polluted by a low-mass (M ∼ 2 − 3 M⊙) AGB star. HD 100503 is potentially identified as a high metallicity analogue of carbon-enhanced metal-poor star enriched in both r- and s-process elements (CEMP-rs).