Dense fluid metallic hydrogen occupies the interiors of Jupiter, Saturn, and many extrasolar planets, where pressures reach millions of atmospheres. Planetary structure models must describe accurately the transition from the outer molecular envelopes to the interior metallic regions. We report optical measurements of dynamically compressed fluid deuterium to 600 gigapascals (GPa) that reveal an increasing refractive index, the onset of absorption of visible light near 150 GPa, and a transition to metal-like reflectivity (exceeding 30%) near 200 GPa, all at temperatures below 2000 kelvin. Our measurements and analysis address existing discrepancies between static and dynamic experiments for the insulator-metal transition in dense fluid hydrogen isotopes. They also provide new benchmarks for the theoretical calculations used to construct planetary models.

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At the 26 th AIRAPT conference in 2017, a task group was formed to work on an International Practical Pressure Scale (IPPS). This report summarizes the activities of the task group toward an IPPS ruby gauge. We have selected three different approaches to establishing the relation between pressure (P) and ruby R1-line shift (Δλ) with three groups of optimal reference materials for applying these approaches. Using a polynomial form of the second order, the recommended ruby gauge (referred as Ruby2020) is expressed by: P[GPa] = 1.87(+0.01) × 10 3 Dl l 0 1 + 5.63(+0.03) Dl l 0 ,where λ 0 is the wavelength of the R1-line near 694.25 nm at ambient condition. In June of 2020, the Executive Committee of AIRAPT endorsed the proposed Ruby2020. We encourage highpressure practitioners to utilize Ruby2020 within its applicable pressure range (up to 150 GPa), so that pressure data can be directly compared across laboratories and amended consistently as better scales emerge in the future.

Dynamic compression by multiple shocks is used to compress iron up to 560 GPa (5.6 Mbar), the highest solid-state pressure yet attained for iron in the laboratory. Extended x-ray absorption fine structure (EXAFS) spectroscopy offers simultaneous density, temperature, and local-structure measurements for the compressed iron. The data show that the close-packed structure of iron is stable up to 560 GPa, the temperature at peak compression is significantly higher than expected from pure compressive work, and the dynamic strength of iron is many times greater than the static strength based on lower pressure data. The results provide the first constraint on the melting line of iron above 400 GPa.

Pressure- and temperature-induced phase transitions have been studied for more than a century but very little is known about the non-equilibrium processes by which the atoms rearrange. Shock compression generates a nearly instantaneous propagating high-pressure/temperature condition while in situ X-ray diffraction (XRD) probes the time-dependent atomic arrangement. Here we present in situ pump–probe XRD measurements on shock-compressed fused silica, revealing an amorphous to crystalline high-pressure stishovite phase transition. Using the size broadening of the diffraction peaks, the growth of nanocrystalline stishovite grains is resolved on the nanosecond timescale just after shock compression. At applied pressures above 18 GPa the nuclueation of stishovite appears to be kinetically limited to 1.4±0.4 ns. The functional form of this grain growth suggests homogeneous nucleation and attachment as the growth mechanism. These are the first observations of crystalline grain growth in the shock front between low- and high-pressure states via XRD.

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Forsterite (Mg 2 SiO 4 ) single crystals were shock compressed to pressures between 200 and 950 GPa using independent plate-impact steady shocks and laser-driven decaying shock compression experiments. Additionally, we performed density functional theory-based molecular dynamics to aid interpretation of the experimental data and to investigate possible phase transformations and phase separations along the Hugoniot. We show that the experimentally obtained Hugoniot cannot distinguish between a pure liquid Mg 2 SiO 4 and an assemblage of solid MgO plus liquid magnesium silicate. The measured reflectivity is nonzero and increases with pressure, which implies that the liquid is a poor electrical conductor at low pressures and that the conductivity increases with pressure.Plain Language Summary Hypervelocity impacts are an important process for planetary and moon formation and evolution. These impact events generate pressures of millions of atmospheres. Forsterite (Mg 2 SiO 4 ) is the magnesium end-member of the olivine series and is a major constituent of the Earth's mantle and likely other terrestrial planets including the recently discovered super-Earths. Here we used Sandia National Laboratories Z Machine and the OMEGA Laser Facility at the University of Rochester to shock compress forsterite to extreme pressures and temperatures. The experiments provide data showing the relationship between pressure, density, and temperature that can be used to construct a model of forsterite's behavior at extreme conditions. Improved knowledge of the properties of forsterite at the extreme pressures created in impacts or in the interiors of super-Earths will help us better understand the formation and interior structure of moons and planets.

The equation of state (EOS) of polystyrene and polypropylene were measured using laser-driven shock waves with pressures from 1 to 10 Mbar. Precision data resulting from the use of α-quartz as an impedance-matching (IM) standard tightly constrains the EOS of these hydrocarbons, even with the inclusion of systematic errors inherent to IM. The temperature at these high pressures was measured, which, combined with kinematic measurements, provide a complete shock EOS. Both hydrocarbons were observed to reach similar compressions and temperatures as a function of pressure. The materials were observed to transition from transparent insulators to reflecting conductors at pressures of 1 to 2 Mbar.