synopsisThe use of a single detector in gel permeation chromatography (GPC) for samples of varying composition leads to erroneous conclusions. With certain simplifying assumptions, a gel permeation chromatograph equipped with properly selected dual detectors yields composition and molecular weight distribution information that is meaningful. Examples discussed are a mixture of homopolymers and a sample supposed to have been a styrene-butadiene block copolymer. The ultraviolet absorption is used in conjunction with the refractive index trace to give qualitative information that is much more informative than could be obtained with one detector. Calibration of the relative responses of the detectors to each of the components of the mixture is described, and these calibrations are used to calculate point-by-point composition, molecular weights, and molecular weight averages.
The determination of cyanide in various forms is important for industrial processes as well as for environmental investigations and monitoring associated with these processes. The accurate determination of cyanide is difficult for various reasons. Depending on the pH of the solution, cyanide is present both in molecular form (HCN) and ionic form (CN). Furthermore, cyanide is a good complexing reagent and reacts with almost all cations resulting in complexes with widely varying properties, such as stabilities, solubilities and rates of reaction. Cyanide also breaks down in sunlight and air, so that sampling and sample treatment become very important aspects to consider in the methodologies. During the last fifty years the determination of cyanide has been approached from various angles and a myriad of methods has been developed for its determination. This study represents a survey of methods commonly used in industrial laboratories for the analysis of cyanide‐containing solutions. An overview of the nomenclature often used for the various forms of cyanides is discussed and the values resulting from a particular analysis will be interpreted. Most common interferences in samples originating from gold processing plants will be discussed.
Supported liquid membranes (SLMs) provide a flexible and selective approach to the separation and enrichment of chemical species. Traditional methods used to optimize the chemical and physical parameters of an SLM system have been found to be tedious and cumbersome. An alternative approach is suggested, and the application of the approach is demonstrated. The proposed approach depends on the optimization of principally the chemical components, with an indication of the impact of physical components on a scaled-down membrane arrangement. An in-situ measurement technique is used to monitor the effect of key parameters on important performance criteria.
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